1-甲氧基-4-苯基乙炔苯合成路线 （共 169 条）
反应条件
potassium phosphate; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide
T=60°C; 2 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Jadhav, Deepak N.; Dasgupta, Priyabrata
Organic Letters, 2010 , vol. 12, # 9 p. 2048 - 2051
反应条件
Na3PO4*12H2O; palladium 10 on activated carbon in water; isopropyl alcohol
T=80°C; 3.5 h; Inert atmosphere;
参考文献
Mori, Shigeki; Takubo, Masato; Yanase, Takayoshi; Maegawa, Tomohiro; Monguchi, Yasunari; Sajiki, Hironao
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 10 p. 1630 - 1634
反应条件
water; potassium carbonate in 1-methyl-pyrrolidin-2-one
T=135°C; Sonogashira Cross-Coupling; 24 h; Catalytic behavior;
参考文献
Leyva-Perez, Antonio; Oliver-Meseguer, Judit; Rubio-Marques, Paula; Corma, Avelino
Angewandte Chemie - International Edition, 2013 , vol. 52, # 44 p. 11554 - 11559
Angew. Chem., 2013 , vol. 125, # 44 p. 11768 - 11773,6
反应条件
MoN(OSi(C6H5)3)3 in bromobenzene-d5
T=180°C; 12 h; Inert atmosphere;
参考文献
Wiedner, Eric S.; Gallagher, Kimberley J.; Johnson, Marc J. A.; Kampf, Jeff W.
Inorganic Chemistry, 2011 , vol. 50, # 13 p. 5936 - 5945
反应条件
1: para-iodoanisole With n-butyllithium in diethyl ether; hexane
Inert atmosphereCooling;
2: 1-(4'-methylphenylsulfonyl)-2-phenylethyne in diethyl ether; hexane
0.25 h; Inert atmosphere; regioselective reaction;
参考文献
Garcia Ruano, Jose Luis; Aleman, Jose; Marzo, Leyre; Alvarado, Cuauhtemoc; Tortosa, Mariola; Diaz-Tendero, Sergio; Fraile, Alberto
Chemistry - A European Journal, 2012 , vol. 18, # 27 p. 8414 - 8422
反应条件
in tetrahydrofuran
T=-78°C; 0.0833333 h;
参考文献
Marzo, Leyre; Aleman, Jose; Garcia Ruano, Jose Luis
Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 4 p. 403 - 407
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-60 - 0°C; 0.5 h; Yield given;
参考文献
Mouries, Virginie; Waschbuesch, Rachel; Carran, John; Savignac, Philippe
Synthesis, 1998 , # 3 p. 271 - 274
反应条件
1: CsCO3; tris(2-furyl)phosphine / Pd2(dba)3 / dioxane; H2O / 6 h / 65 °C
2: Bu4N(OH)*30H2O / dioxane; H2O / 1 h / 65 °C
View Scheme
参考文献
Chelucci, Giorgio; Capitta, Francesca; Baldino, Salvatore; Pinna, Gerard A.
Tetrahedron Letters, 2007 , vol. 48, # 37 p. 6514 - 6517
反应条件
1: CsCO3; tris(2-furyl)phosphine / Pd2(dba)3 / dioxane; H2O / 6 h / 65 °C
2: Bu4N(OH)*30H2O / dioxane; H2O / 1 h / 65 °C
View Scheme
参考文献
Chelucci, Giorgio; Capitta, Francesca; Baldino, Salvatore; Pinna, Gerard A.
Tetrahedron Letters, 2007 , vol. 48, # 37 p. 6514 - 6517
反应条件
1: 85 percent / K3PO4; N-(2-diphenylphosphinobenzylidene)-2-phenylethylamine / Pd(OAc)2 / dimethylsulfoxide / 24 h / 80 °C
2: 84 percent / K3PO4; triphenylphosphine / Pd(OAc)2 / dimethylsulfoxide / 24 h / 80 °C
View Scheme
参考文献
Shirakawa, Eiji; Kitabata, Takaaki; Otsuka, Hidehito; Tsuchimoto, Teruhisa
Tetrahedron, 2005 , vol. 61, # 41 p. 9878 - 9885
