4-溴-N,N-二甲基苯胺溴化镁合成路线 （共 37 条）
反应条件
air in tetrahydrofuran T=-25°C; P=12929 Torr; 0.0566667 h; Green chemistry;
参考文献
He, Zhi; Jamison, Timothy F.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 13 p. 3353 - 3357
Angew. Chem., 2014 , vol. 126, # 13 p. 3421 - 3425,5
反应条件
in dichloromethane T=0°C; Substitution;
参考文献
Guzman, Angel; Alfaro, Ricardo; Diaz, Eduardo
Synthetic Communications, 1999 , vol. 29, # 17 p. 3021 - 3024
反应条件
1: p-toluidine With n-butyllithium; ZnCl2*TMEDA in tetrahydrofuran; hexane T=0 - 20°C; 0.5 h; Inert atmosphereSchlenk technique; 2: [4-(N,N-dimethylamino)-phenyl]-magnesium bromide With N,N'-dimethyl-N,N'-propyleneurea; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane in tetrahydrofuran; hexane T=0 - 20°C; 3 h; Inert atmosphereSchlenk technique;
参考文献
Ilies, Laurean; Matsubara, Tatsuaki; Nakamura, Eiichi
Organic Letters, 2012 , vol. 14, # 21 p. 5570 - 5573,4
反应条件
2: 80 percent / CHCl3 / 2 h / Irradiation; steady state photolysis; photoinduced electron transfer retropinacolon reaction of 4-(N,N-dimethylamino)phenyl pinacols in CHCl3; cleavage of central C-C bond; fluorescence and NMR study; fluorescence quenching rate constant View Scheme
参考文献
Zhang, Wei; Yang, Li; Wu, Long-Min; Liu, You-Cheng; Liu, Zhong-Li
Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 5 p. 1189 - 1193
反应条件
C32H26ClN2NiP in tetrahydrofuran
T=30°C; Kumada Cross-Coupling; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Xue-Qi; Wang, Zhong-Xia
Synlett, 2013 , vol. 24, # 16 art. no. ST-2013-W0528-L, p. 2081 - 2084
反应条件
Ni(PCy3)2Cl2; tri-cyclo-hexyl-phosphine in various solvent(s)
T=70°C; 15 h;
参考文献
Dankwardt, John W.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 18 p. 2428 - 2432
反应条件
C35H31BrN4NiP in tetrahydrofuran
T=25°C; 12 h; Schlenk techniqueInert atmosphere;
参考文献
Guo, Wang-Jun; Wang, Zhong-Xia
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 1054 - 1061
反应条件
C68H72Cl2N6NiP2 in toluene
T=120°C; 16 h; Inert atmosphere;
参考文献
Xie, Lan-Gui; Wang, Zhong-Xia
Chemistry - A European Journal, 2011 , vol. 17, # 18 p. 4972 - 4975
反应条件
C32H26ClN2NiP in tetrahydrofuran
T=30°C; Kumada Cross-Coupling; 12 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Xue-Qi; Wang, Zhong-Xia
Synlett, 2013 , vol. 24, # 16 art. no. ST-2013-W0528-L, p. 2081 - 2084
反应条件
1: [4-(N,N-dimethylamino)-phenyl]-magnesium bromide With [Ni0(1,5-cyclooctadiene)2]; SIDip*HCl in tetrahydrofuran
T=0°C; 0.166667 h;
2: (cyclohexylsulfanyl)benzene in tetrahydrofuran
T=0 - 60°C; 3.16667 h;
参考文献
Ishizuka, Kentaro; Seike, Hirofumi; Hatakeyama, Takuji; Nakamura, Masaharu
Journal of the American Chemical Society, 2010 , vol. 132, # 38 p. 13117 - 13119
