4-溴-N,N-二甲基苯胺溴化镁合成路线 （共 37 条）
反应条件
in tetrahydrofuran react. at -65°C, 12h at room temp., hydrolysis with H2O, addn. of dild. H2So4 until pH 3-4, extractn. with ether, neutralization of aq. and organic phase with NH3;; extractn. of impurities with petroleum ether;;
参考文献
Gmelin Handbook: B: B-Verb.13, 4.7.2.6, page 219 - 226
反应条件
Fe(acac)3 in tetrahydrofuran T=25°C; 3 h; Inert atmosphere;
参考文献
Volla, Chandra M. R.; Markovic, Dean; Dubbaka, Srinivas Reddy; Vogel, Pierre
European Journal of Organic Chemistry, 2009 , # 36 p. 6281 - 6288
反应条件
N,N,N',N,-tetramethylethylenediamine; ((Me)N2N)Ni-Cl in tetrahydrofuran T=20°C; Kumada-Corriu-Tamao coupling reaction; 2 h; Inert atmosphere;
参考文献
Vechorkin, Oleg; Proust, Valerie; Hu, Xile
Journal of the American Chemical Society, 2009 , vol. 131, # 28 p. 9756 - 9766
反应条件
C35H31BrN4NiP in tetrahydrofuran T=25°C; 12 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Xue-Qi; Wang, Zhong-Xia
Synlett, 2013 , vol. 24, # 16 art. no. ST-2013-W0528-L, p. 2081 - 2084
反应条件
C68H72Cl2N6NiP2 in tetrahydrofuran T=25°C; 24 h; Inert atmosphere;
参考文献
Xie, Lan-Gui; Wang, Zhong-Xia
Chemistry - A European Journal, 2011 , vol. 17, # 18 p. 4972 - 4975
反应条件
C35H31BrN4NiP in tetrahydrofuran T=25°C; 12 h; Schlenk techniqueInert atmosphere;
参考文献
Guo, Wang-Jun; Wang, Zhong-Xia
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 1054 - 1061
反应条件
nickel Inert atmosphere;
参考文献
Gao, Ke; Lee, Pin-Sheng; Fujita, Takeshi; Yoshikai, Naohiko
Journal of the American Chemical Society, 2010 , vol. 132, # 35 p. 12249 - 12251
反应条件
C68H72Cl2N6NiP2 in tetrahydrofuran T=50°C; 12 h; Inert atmosphere;
参考文献
Xie, Lan-Gui; Wang, Zhong-Xia
Chemistry - A European Journal, 2011 , vol. 17, # 18 p. 4972 - 4975
反应条件
oxygen; lithium chloride; manganese (II) chloride in tetrahydrofuran T=-5 - 0°C; Inert atmosphere; chemoselective reaction;
参考文献
Angewandte Chemie, International Edition, , vol. 48, # 36 p. 6731 - 6734
反应条件
in tetrahydrofuran T=1°C; 0.0833333 h;
参考文献
Mutule, Ilga; Suna, Edgars
Tetrahedron, 2005 , vol. 61, # 47 p. 11168 - 11176
