2-甲基-1,3-苯并噻唑1,1-二氧化物合成路线 （共 5 条）
反应条件
trichlorophosphate
T=20 - 130°C; 3 h;
参考文献
Reichardt, Christian; Erfurt, Hans-Peter; Harms, Klaus
Phosphorus, Sulfur and Silicon and the Related Elements, 2003 , vol. 178, # 5 p. 1081 - 1092
反应条件
1: 68 percent / benzene / 1 h / 90 °C
2: 5 mg / POCl3 / 3 h / 20 - 130 °C
View Scheme
参考文献
Reichardt, Christian; Erfurt, Hans-Peter; Harms, Klaus
Phosphorus, Sulfur and Silicon and the Related Elements, 2003 , vol. 178, # 5 p. 1081 - 1092
反应条件
trichlorophosphate
T=130°C;
参考文献
Zincke; Siebert
Chemische Berichte, 1915 , vol. 48, p. 1247
反应条件
1: 52 percent / aq. NaOH / 2 h / Heating
2: 68 percent / benzene / 1 h / 90 °C
3: 5 mg / POCl3 / 3 h / 20 - 130 °C
View Scheme
参考文献
Reichardt, Christian; Erfurt, Hans-Peter; Harms, Klaus
Phosphorus, Sulfur and Silicon and the Related Elements, 2003 , vol. 178, # 5 p. 1081 - 1092
反应条件
1: zinc; concentrated hydrochloric acid
2: sodium acetate
3: glacial acetic acid; hydrogen peroxide
4: phosphorus oxychloride / 130 °C
View Scheme
参考文献
Zincke; Siebert
Chemische Berichte, 1915 , vol. 48, p. 1247
