2,2':5',2'-四噻吩-5-甲醛合成路线 (共 20 条)
反应条件
Na3PO4*12H2O; palladium 10 on activated carbon in isopropyl alcohol T=80°C; 4 h;
参考文献
COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION; THE UNIVERSITY OF MELBOURNE; MONASH UNIVERSITY; SECURENCY INTERNATIONAL PTY LTD; EVANS, Richard; GUPTA, Akhil; ALI, Abdelselam Saeed
Patent: WO2011/137487 A1, 2011 ;
Location in patent: Page/Page column 23-24 ;
反应条件
1: With trichlorophosphate T=0 - 50°C; 2 h; 2: With water; sodium acetate
参考文献
Tetrahedron, , vol. 68, # 18 p. 3605 - 3610
反应条件
1: N,N-dimethyl-formamide With trichlorophosphate in dichloromethane T=40°C; 0.5 h; 2: alpha-Terthiophene in dichloromethane T=20°C; 28 h; Further stages.;
参考文献
Nishizawa, Takeshi; Tajima, Keisuke; Hashimoto, Kazuhito
Journal of Materials Chemistry, 2007 , vol. 17, # 23 p. 2440 - 2445
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether T=80°C; Suzuki cross-coupling reaction;
参考文献
Batista, Rosa M.F.; Costa, Susana P.G.; Belsley; Lodeiro, Carlos; Raposo, M. Manuela M.
Tetrahedron, 2008 , vol. 64, # 39 p. 9230 - 9238
反应条件
triphenyl-arsane; tris(dibenzylideneacetone)dipalladium (0) in toluene 4 h; Heating;
参考文献
Albano, Vincenzo Giulio; Bandini, Marco; Melucci, Manuela; Monari, Magda; Piccinelli, Fabio; Tommasi, Simona; Umani-Ronchi, Achille
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 11-13 p. 1507 - 1512
反应条件
sodium carbonate; bis-triphenylphosphine-palladium(II) chloride in ethylene glycol dimethyl ether; ethanol Suzuki reaction; 48 h; Heating;
参考文献
Bandini, Marco; Melucci, Manuela; Piccinelli, Fabio; Sinisi, Riccardo; Tommasi, Simona; Umani-Ronchi, Achille
Chemical Communications, 2007 , # 43 p. 4519 - 4521
反应条件
trichlorophosphate in dichloromethane 24 h; Ambient temperature;
参考文献
Eachern, Anita Mac; Soucy, Chantal; Leitch, Leonard C.; Arnason, John T.; Morand, Peter
Tetrahedron, 1988 , vol. 44, # 9 p. 2403 - 2412
反应条件
potassium fluoride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in methanol; toluene T=70°C; Suzuki coupling; 0.166667 h; microwave irradiation;
参考文献
Journal of Organic Chemistry, , vol. 69, # 14 p. 4821 - 4828
反应条件
trichlorophosphate in dichloromethane 48 h; Ambient temperature;
参考文献
Tetrahedron, , vol. 44, # 9 p. 2403 - 2412
反应条件
1: NIS / dimethylformamide / -20 °C 2: KF / PdCl2dppf / toluene; methanol / 0.17 h / 70 °C / microwave irradiation View Scheme
参考文献
Journal of Organic Chemistry, , vol. 69, # 14 p. 4821 - 4828