(2E,4E)-2,4-癸二烯酸甲酯合成路线 （共 56 条）
反应条件
aluminum oxide in o-xylene
T=160°C; 2 h; Inert atmosphere;
参考文献
Mori, Kenji
Tetrahedron, 2012 , vol. 68, # 7 p. 1936 - 1946
反应条件
tetrabutyl-ammonium chloride; palladium diacetate; potassium carbonate in N,N-dimethyl-formamide
T=20°C; Heck reaction; 1 h; Inert atmosphere;
参考文献
Mori, Kenji
Tetrahedron, 2012 , vol. 68, # 7 p. 1936 - 1946
反应条件
triphenylphosphine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in toluene
T=20°C; 0.25 h;
参考文献
Tanikaga, Rikuhei; Takeuchi, Jun; Takyu, Masayuki; Kaji, Aritsune
Journal of the Chemical Society, Chemical Communications, 1987 , # 5 p. 386 - 387
反应条件
sodium hydride in N,N-dimethyl-formamide
16 h; Ambient temperature;
参考文献
Banerji, Avijit; Pal, Sudhir C.
Phytochemistry (Elsevier), 1983 , vol. 22, # 4 p. 1028 - 1030
反应条件
1: 1.) diisobutylaluminium hydride, 2.) I2
2: potassium carbonate, tetrabutylammonium bromide, palladium acetate / 5 h / Ambient temperature
View Scheme
参考文献
Jeffery, Tuyet
Synthetic Communications, 1988 , vol. 18, # 1 p. 77 - 84
反应条件
in dichloromethane
T=20°C; Inert atmosphere;
参考文献
Zhang, Ping; Morken, James P.
Journal of the American Chemical Society, 2009 , vol. 131, # 35 p. 12550 - 12551
反应条件
1: pyridine / Erhitzen des Reaktionsgemisches
2: petroleum ether; thionyl chloride
View Scheme
参考文献
Jacobson
Journal of the American Chemical Society, 1953 , vol. 75, p. 2584 Anm. 11
反应条件
1: piperidine
2: DMAP
3: 24 percent / Ph3P / Pd2(dba)3*CHCl3 / toluene / 0.25 h / 20 °C
View Scheme
参考文献
Tanikaga, Rikuhei; Takeuchi, Jun; Takyu, Masayuki; Kaji, Aritsune
Journal of the Chemical Society, Chemical Communications, 1987 , # 5 p. 386 - 387
反应条件
1: 28 percent / Ph3P / Pd2(dba)3*CHCl3 / toluene / 0.25 h / 55 °C
2: DMAP
3: 24 percent / Ph3P / Pd2(dba)3*CHCl3 / toluene / 0.25 h / 20 °C
View Scheme
参考文献
Tanikaga, Rikuhei; Takeuchi, Jun; Takyu, Masayuki; Kaji, Aritsune
Journal of the Chemical Society, Chemical Communications, 1987 , # 5 p. 386 - 387
反应条件
potassium hydride in tetrahydrofuran
T=-78 - -40°C; Yield given. Yields of byproduct given;
参考文献
Sato, Toshio; Tsunekawa, Hiroshi; Kohama, Hiromasa; Fujisawa, Tamotsu
Chemistry Letters, 1986 , p. 1553 - 1556
