2,5-二甲氧基苯-1,4-二甲醛合成路线 （共 18 条）
反应条件
1: 2,5-dibromo-1,4-dimethoxybenzene With n-butyllithium in tetrahydrofuran T=-78°C; 2: (4-morpholinyl)methanone in tetrahydrofuran T=-78°C;
参考文献
Hwang, Gil Tae; Son, Hyung Su; Ku, Ja Kang; Kim, Byeang Hyean
Journal of the American Chemical Society, 2003 , vol. 125, # 37 p. 11241 - 11248
反应条件
1: 1,4-dimethoxy benzene With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in diethyl ether; hexane T=-78°C; 2 h; 2: N,N-dimethyl-formamide in tetrahydrofuran; diethyl ether; hexane T=20°C; 0.5 h; Further stages.;
参考文献
Hiremath, Uma S.
Tetrahedron Letters, 2013 , vol. 54, # 26 p. 3419 - 3423
反应条件
1: 2,5-dibromo-1,4-dimethoxybenzene With n-butyllithium in tetrahydrofuran T=-80°C; Inert atmosphere; 2: N,N-dimethyl-formamide in tetrahydrofuran T=-80°C;
参考文献
Tylleman, Benoit; Velde, Christophe M.L. Vande; Balandier, Jean-Yves; Stas, Sara; Sergeyev, Sergey; Geerts, Yves Henri
Organic Letters, 2011 , vol. 13, # 19 p. 5208 - 5211
反应条件
dipotassium hydrogenphosphate; Potassium benzeneselenite in acetonitrile 16 h;
参考文献
Syper; Mlochowski
Synthesis, 1984 , vol. NO. 9, p. 747 - 752
反应条件
1.1: 96 percent / Br2 / CCl4 / 0 °C 2.1: n-BuLi / tetrahydrofuran / -78 °C 2.2: 75 percent / tetrahydrofuran / -78 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 125, # 37 p. 11241 - 11248
反应条件
1: With 1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane in chloroform 16 h; Reflux; 2: With formaldehyd; water 21 h; Reflux;
参考文献
Lee, Sumi; Ahn, Tae-Young; Kim, Sangjun; Jung, Young-Sik; Kim, Jong-Man
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 10 p. 2755 - 2756
反应条件
1: With 1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane in chloroform Sommelet reaction; 3 h; Heating; 2: With hydrogenchloride T=20°C; Further stages.;
参考文献
Kretz, Tonia; Bats, Jan Willem; Lerner, Hans-Wolfram; Wagner, Matthias
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2007 , vol. 62, # 1 p. 66 - 74
反应条件
1: With potassium hydroxide in methanol Electrolysis; 2: With sulfuric acid in acetone
参考文献
Zeng, Cheng-Chu; Becker, James Y.
Journal of Organic Chemistry, 2004 , vol. 69, # 4 p. 1053 - 1059
反应条件
formaldehyd in water 21 h; Heating;
参考文献
Leighton, Philip; Sanders, Jeremy K. M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 2385 - 2394
反应条件
1: With potassium hydroxide in methanol Electrolysis; 2: With sulfuric acid in acetone
参考文献
Zeng, Cheng-Chu; Becker, James Y.
Journal of Organic Chemistry, 2004 , vol. 69, # 4 p. 1053 - 1059
