copper acetylacetonate; oxygen; benzoic acid in acetonitrile T=50°C; 12 h;

chloro-trimethyl-silane in acetonitrile 118 h; Ambient temperature;

in water T=0 - 20°C;

lithium aluminium tetrahydride in diethyl ether 24 h; Heating;

lithium aluminium tetrahydride in tetrahydrofuran 24 h; Heating;

lithium aluminium tetrahydride in diethyl ether 24 h; Heating;

sodium hydride in N,N,N',N',N'',N''-hexamethylphosphoric triamide; benzene 24 h; Heating;

sodium hydride in N,N,N',N',N'',N''-hexamethylphosphoric triamide; benzene 24 h; Heating;

1: 78 percent / p-toluenesulfonic acid / 120 h / Heating 2: 81 percent / hydrazine hydrate / ethanol / 10 h / Heating 3: conc. hydrochloric acid, sodium nitrite / H2O; CHCl3 / -5 °C 4: CHCl3 / 50 °C 5: 70 percent / conc. hydrochloric acid / CHCl3 6: conc. hydrochloric acid, sodium nitrite / H2O / -6 °C 7: 70 percent / LiAlH4 / tetrahydrofuran / 24 h / Heating View Scheme

1: sodium azide / H2O; acetone / 0 °C 2: CHCl3 / 50 °C 3: 70 percent / conc. hydrochloric acid / CHCl3 4: conc. hydrochloric acid, sodium nitrite / H2O / -6 °C 5: 70 percent / LiAlH4 / tetrahydrofuran / 24 h / Heating View Scheme