1,3,5-三(三氟甲基)苯合成路线 （共 24 条）
反应条件
sulfur(IV) fluoride T=170°C; 48 h;
参考文献
Scholz, Mario; Roesky, Herbert W.; Stalke, Dietmar; Keller, Klaus; Edelmann, Frank T.
Journal of Organometallic Chemistry, 1989 , vol. 366, p. 73 - 86
反应条件
copper(l) iodide in N,N-dimethyl-formamide T=150°C; 6 h;
参考文献
Porwisiak, Jacek; Schlosser, Manfred
Chemische Berichte, 1996 , vol. 129, # 2 p. 233 - 235
反应条件
[PdCl2(AsPh3)2]; [AuCl(AsPh3)]; triphenyl-arsane; lithium chloride in acetonitrile T=80°C; Stille Cross Coupling; 48 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 8 p. 2189 - 2193
Angew. Chem., , vol. 125, # 8 p. 2245 - 2249
反应条件
lt;Rh(μ-SC6F5)(COD)gt;2 in benzene 1 h; Ambient temperaturevar. catalyst: <Rh(μ-SC6F4H-p)(COD)>2 or <Rh(μ-SC6H4F-p)(COD)>2; var. solv.: toluene, acetone; Product distribution;
参考文献
Garcia, Juventino J.; Sierra, Carmen; Torrens, Hugo
Tetrahedron Letters, 1996 , vol. 37, # 34 p. 6097 - 6098
反应条件
hydrogen fluoride T=200°C;
参考文献
Industrial and Engineering Chemistry, , vol. 39, p. 393
反应条件
1: 87 percent / 96percent H2SO4, N,N'-dibromo-5,5-dimethylhydantoin / 24 h / 0 °C 2: 72 percent / CuI / dimethylformamide / 6 h / 150 °C View Scheme
参考文献
Chemische Berichte, , vol. 129, # 2 p. 233 - 235
反应条件
1-methyl-pyrrolidin-2-one; copper(l) iodide T=160°C; 4 h;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 921 - 926
反应条件
carbon oxide sulfide T=150°C; Irradiation; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Canadian Journal of Chemistry, , vol. 61, p. 2268 - 2281
反应条件
carbon oxide sulfide T=150°C; Irradiation; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Canadian Journal of Chemistry, , vol. 61, p. 2268 - 2281
反应条件
1: chlorine / 150 °C / Irradiation 2: HF / 200 °C View Scheme
参考文献
Industrial and Engineering Chemistry, , vol. 39, p. 393
