3-氯-9H-芴-9-酮合成路线 （共 20 条）
反应条件
dipotassium peroxodisulfate; silver(I) acetate in acetonitrile-D3
T=130°C; Pschorr reaction; 1 h; Microwave irradiation;
参考文献
Seo, Sangwon; Slater, Mark; Greaney, Michael F.
Organic Letters, 2012 , vol. 14, # 10 p. 2650 - 2653
反应条件
palladium diacetate; silver(l) oxide in trifluoroacetic acid
T=130°C; 30 h; Inert atmosphere;
参考文献
Gandeepan, Parthasarathy; Hung, Chen-Hsun; Cheng, Chien-Hong
Chemical Communications, 2012 , vol. 48, # 75 p. 9379 - 9381
反应条件
dichloro bis(acetonitrile) palladium(II); water; silver(l) oxide in N,N-dimethyl acetamide; trifluoroacetic acid
T=140°C; Heck Reaction; 96 h; GloveboxInert atmosphere;
参考文献
Wan, Jung-Chih; Huang, Jun-Min; Jhan, Yu-Huei; Hsieh, Jen-Chieh
Organic Letters, 2013 , vol. 15, # 11 p. 2742 - 2745
反应条件
1.1: magnesium / tetrahydrofuran / 2 h / 20 - 85 °C
1.2: 0 - 20 °C / |Inert atmosphere
2.1: pyridinium chlorochromate; triethylamine / dichloromethane / 20 °C
3.1: palladium diacetate; trifluoroacetic acid; potassium carbonate; silver(l) oxide / 24 h / 140 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Li, Hu; Zhu, Ru-Yi; Shi, Wen-Juan; He, Ke-Han; Shi, Zhang-Jie
Organic Letters, 2012 , vol. 14, # 18 p. 4850 - 4853,4
反应条件
1.1: magnesium / tetrahydrofuran / 2 h / 20 - 85 °C
1.2: 0 - 20 °C / |Inert atmosphere
2.1: pyridinium chlorochromate; triethylamine / dichloromethane / 20 °C
3.1: palladium diacetate; trifluoroacetic acid; potassium carbonate; silver(l) oxide / 24 h / 140 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Li, Hu; Zhu, Ru-Yi; Shi, Wen-Juan; He, Ke-Han; Shi, Zhang-Jie
Organic Letters, 2012 , vol. 14, # 18 p. 4850 - 4853,4
反应条件
1: pyridinium chlorochromate; triethylamine / dichloromethane / 20 °C
2: palladium diacetate; trifluoroacetic acid; potassium carbonate; silver(l) oxide / 24 h / 140 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Li, Hu; Zhu, Ru-Yi; Shi, Wen-Juan; He, Ke-Han; Shi, Zhang-Jie
Organic Letters, 2012 , vol. 14, # 18 p. 4850 - 4853,4
反应条件
Wilkinson's catalyst
T=240°C;
参考文献
Blum,J. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 3233 - 3237
反应条件
1: palladium diacetate; potassium carbonate / water; N,N-dimethyl-formamide / 1 h / 20 °C
2: IPy2BF4; tetrafluoroboric acid / dichloromethane; diethyl ether / 24 h / -70 °C
3: palladium diacetate; triphenylphosphine; triethylamine / water; N,N-dimethyl-formamide / 16 h / 130 °C / |Inert atmosphere
View Scheme
参考文献
Sarkar, Satinath; Jana, Manoranjan; Narender, Tadigoppula
European Journal of Organic Chemistry, 2013 , # 29 p. 6491 - 6495
反应条件
1: palladium diacetate; potassium carbonate / water; N,N-dimethyl-formamide / 1 h / 20 °C
2: IPy2BF4; tetrafluoroboric acid / dichloromethane; diethyl ether / 24 h / -70 °C
3: palladium diacetate; triphenylphosphine; triethylamine / water; N,N-dimethyl-formamide / 16 h / 130 °C / |Inert atmosphere
View Scheme
参考文献
Sarkar, Satinath; Jana, Manoranjan; Narender, Tadigoppula
European Journal of Organic Chemistry, 2013 , # 29 p. 6491 - 6495
参考文献
Bolton, Roger; Mguni, Raphael S.; Williams, Gareth H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 405 - 408
