ammonia; hydrogen; palladium on activated charcoal in methanol P=750.06 Torr; 12 h; Ambient temperature;

1: 76 percent / PCl5 / 2 h / 115 - 120 °C 2: 84 percent / bis-(2-methoxy-ethyl) ether / 17 h / 160 °C 3: 83 percent / H2, NH3 / 10percent Pd/C / methanol / 12 h / 750.06 Torr / Ambient temperature View Scheme

1: 84 percent / bis-(2-methoxy-ethyl) ether / 17 h / 160 °C 2: 83 percent / H2, NH3 / 10percent Pd/C / methanol / 12 h / 750.06 Torr / Ambient temperature View Scheme

1: 67 percent / 20percent aq. NaOCl / methanol / 1.5 h / 50 °C 2: 84 percent / bis-(2-methoxy-ethyl) ether / 17 h / 160 °C 3: 83 percent / H2, NH3 / 10percent Pd/C / methanol / 12 h / 750.06 Torr / Ambient temperature View Scheme