2-氧杂螺[4.5]癸烷-3-酮合成路线 （共 9 条）
参考文献
Windaus; Klaenhardt; Reverey
Chemische Berichte, 1922 , vol. 55, p. 3987
参考文献
Windaus; Klaenhardt; Reverey
Chemische Berichte, 1922 , vol. 55, p. 3987
反应条件
sodium hydroxide; dihydrogen peroxide in methanol
2 h; Ambient temperature; Yield given;
参考文献
Picard, Philippe; Moulines, Jean; Lecoustre, Max
Bulletin de la Societe Chimique de France, 1984 , vol. 2, # 1-2 p. 65 - 70
反应条件
1: 1.) diisopropylamine, butyllithium / 1.) THF, -10 deg C, 1 h; 2.) THF, RT, 12 h
2: LiAlH4 / diethyl ether / 1 h / Heating
View Scheme
参考文献
Picard, Philippe; Moulines, Jean; Lecoustre, Max
Bulletin de la Societe Chimique de France, 1984 , vol. 2, # 1-2 p. 65 - 70
反应条件
1: NH4Cl, Zn / 2-methyl-propan-2-ol / 12 h / 65 °C
2: 30percent H2O2, NaOH / methanol / 2 h / Ambient temperature
View Scheme
参考文献
Picard, Philippe; Moulines, Jean; Lecoustre, Max
Bulletin de la Societe Chimique de France, 1984 , vol. 2, # 1-2 p. 65 - 70
反应条件
1: LiAlH4 / diethyl ether / 1 h / Heating
View Scheme
参考文献
Picard, Philippe; Moulines, Jean; Lecoustre, Max
Bulletin de la Societe Chimique de France, 1984 , vol. 2, # 1-2 p. 65 - 70
反应条件
1: Zn / diethyl ether / 5 h / Heating
2: NH4Cl, Zn / 2-methyl-propan-2-ol / 12 h / 65 °C
3: 30percent H2O2, NaOH / methanol / 2 h / Ambient temperature
View Scheme
参考文献
Picard, Philippe; Moulines, Jean; Lecoustre, Max
Bulletin de la Societe Chimique de France, 1984 , vol. 2, # 1-2 p. 65 - 70
反应条件
Yield given. Multistep reaction;
参考文献
Picard, Philippe; Moulines, Jean; Lecoustre, Max
Bulletin de la Societe Chimique de France, 1984 , vol. 2, # 1-2 p. 65 - 70
参考文献
Schinz; Hinder
Helvetica Chimica Acta, 1947 , vol. 30, p. 1349,1366
