5-甲氧基-1,3-苯并二恶茂合成路线 （共 19 条）
反应条件
1: phosphorus oxychloride / chlorobenzene / 24 h / Ambient temperature 2: 80 percent / 85percent formic acid; 30percent H2O2 / 16 h / 5 °C View Scheme
参考文献
Devakumar, C.; Saxena, V. S.; Mukerjee, S. K.
Agricultural and Biological Chemistry, 1985 , vol. 49, # 3 p. 725 - 730
反应条件
1: phosphorus oxychloride / chlorobenzene / 24 h / Ambient temperature 2: 80 percent / 85percent formic acid; 30percent H2O2 / 16 h / 5 °C 3: anh. K2CO3 / acetone / 6 h / Heating View Scheme
参考文献
Devakumar, C.; Saxena, V. S.; Mukerjee, S. K.
Agricultural and Biological Chemistry, 1985 , vol. 49, # 3 p. 725 - 730
反应条件
potassium carbonate in acetone
42 h; Heating;
参考文献
Schuda, Paul Francis; Price, William A.
Journal of Organic Chemistry, 1987 , vol. 52, # 10 p. 1972 - 1979
反应条件
sodium hydroxide in water
1 h; Heating;
参考文献
Aslam, Shazia N.; Stevenson, Philip C.; Phythian, Sara J.; Veitch, Nigel C.; Hall, David R.
Tetrahedron, 2006 , vol. 62, # 17 p. 4214 - 4226
反应条件
1: 3,4-(methylenedioxy)phenol With tetraethylammonium hydroxide in methanol
2: dimethylsulfide in tetrahydrofuran
T=20°C; 1 h;
参考文献
Bernet, Andreas; Seifert, Karlheinz
Helvetica Chimica Acta, 2006 , vol. 89, # 4 p. 784 - 796
反应条件
formic acid methyl ester; copper(l) chloride in methanol
T=110°C; 2 h; Autoclave;
参考文献
Jiang, Jian-An; Chen, Cheng; Guo, Ying; Liao, Dao-Hua; Pan, Xian-Dao; Ji, Ya-Fei
Green Chemistry, 2014 , vol. 16, # 5 p. 2807 - 2814
反应条件
tris-(dibenzylideneacetone)dipalladium(0); di-tert-butyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine in N,N-dimethyl-formamide
T=100°C; Inert atmosphere;
参考文献
Tolnai, Gergely L.; Petho, Balint; Krall, Peter; Novaka, Zoltan
Advanced Synthesis and Catalysis, 2014 , vol. 356, # 1 p. 125 - 129
反应条件
copper(l) iodide; diisopropylamine; bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide
T=60°C; 1 h;
参考文献
Aslam, Shazia N.; Stevenson, Philip C.; Phythian, Sara J.; Veitch, Nigel C.; Hall, David R.
Tetrahedron, 2006 , vol. 62, # 17 p. 4214 - 4226
反应条件
1: 35 percent / 85percent formic acid; 30percent H2O2 / 16 h / 5 °C
2: anh. K2CO3 / acetone / Heating
View Scheme
参考文献
Devakumar, C.; Saxena, V. S.; Mukerjee, S. K.
Agricultural and Biological Chemistry, 1985 , vol. 49, # 3 p. 725 - 730
反应条件
1: 1.8 g / AlCl3 / diethyl ether / 21 h
2: 80 mg / sodium hydroxide / methanol; H2O / 6 h / Heating
View Scheme
参考文献
Balachandran, Sarala; Vishwakarma, R. A.; Popli, S. P.; Kapil, R. S.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1988 , vol. 27, # 1-12 p. 385 - 386
