5,6-二氯吡啶-3-甲醛合成路线 (共 5 条)
反应条件
manganese(IV) oxide in dichloromethane T=25°C; 48 h;
参考文献
Tafesse, Laykea
Patent: US2010/120862 A1, 2010 ;
Location in patent: Page/Page column 94 ;
US 20100120862 A1
反应条件
diisobutylaluminium hydride in toluene T=-30°C; 0.5 h;
参考文献
WO2008/75757 A1, ;
Page/Page column 36 ;
WO 2008/075757 A1
反应条件
1: With oxalyl dichloride; N,N-dimethyl-formamide in tetrahydrofuran; pyridine; acetonitrile T=-30°C; 1.5 h; 2: With copper(l) iodide; tri-tert-butoxyaluminum hydride in tetrahydrofuran; pyridine; acetonitrile T=-78°C; 0.25 h;
参考文献
Felpin, Francois-Xavier; Bertrand, Marie-Jo; Lebreton, Jacques
Tetrahedron, 2002 , vol. 58, # 37 p. 7381 - 7389
反应条件
Pd-BaSO4; xylene T=160 - 170°C; Hydrogenation;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. <2>134, p. 177,184
参考文献
Graf
Journal fuer Praktische Chemie (Leipzig), 1932 , vol. <2>134, p. 177,184