2,4-二甲氧基-6-甲基苯甲醛合成路线 （共 20 条）
反应条件
boron trichloride in dichloromethane
参考文献
Djura,P. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 147 - 151
反应条件
1.1: 4.15 g / NaH2PO4; NaClO2 / dimethylsulfoxide; H2O / 20 °C 2.1: 99 percent / DBU / acetonitrile / 20 °C 3.1: LDA / tetrahydrofuran; hexane / 0.33 h / -78 °C 3.2: 70 percent / tetrahydrofuran; hexane / -78 - 20 °C View Scheme
参考文献
Wang, Ping; Zhang, Zhaojun; Yu, Biao
Journal of Organic Chemistry, 2005 , vol. 70, # 22 p. 8884 - 8889
反应条件
sodium chlorite; sodium dihydrogenphosphate in water; dimethyl sulfoxide
Ambient temperature;
参考文献
Solladie; Rubio; Carreno; Ruano
Tetrahedron Asymmetry, 1990 , vol. 1, # 3 p. 187 - 198
反应条件
und Erhitzen des Reaktionsprodukts mit Wasser,Zink-Pulver und AgNO3;
参考文献
Spaeth; Pailer; Gergely
Chemische Berichte, 1940 , vol. 73, p. 795,802
反应条件
sulfuric acid; dihydrogen peroxide in methanol; water
T=0°C; 0.333333 h;
参考文献
Buccini, Marco; Punch, Kathryn A.; Kaskow, Belinda; Flematti, Gavin R.; Skelton, Brian W.; Abraham, Lawrence J.; Piggott, Matthew J.
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 7 p. 1100 - 1113
反应条件
chloroform; ozone
T=0°C; Erhitzen der Reaktionsprodukte mit Wasser und Zink-Pulver unter Zusatz von AgNO3;
参考文献
Spaeth; Pailer; Gergely
Chemische Berichte, 1940 , vol. 73, p. 795,802
反应条件
und Erhitzen des Reaktionsprodukts mit Wasser,Zink-Pulver und AgNO3;
参考文献
Spaeth; Pailer; Gergely
Chemische Berichte, 1940 , vol. 73, p. 795,802
反应条件
sulfuric acid; dihydrogen peroxide in methanol; water
T=0°C; 0.333333 h;
参考文献
Buccini, Marco; Punch, Kathryn A.; Kaskow, Belinda; Flematti, Gavin R.; Skelton, Brian W.; Abraham, Lawrence J.; Piggott, Matthew J.
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 7 p. 1100 - 1113
反应条件
1: dihydrogen peroxide; sulfuric acid / methanol; water / 0.33 h / 0 °C
2: potassium carbonate / N,N-dimethyl-formamide / 24 h / |Inert atmosphere; |Darkness
View Scheme
参考文献
Buccini, Marco; Punch, Kathryn A.; Kaskow, Belinda; Flematti, Gavin R.; Skelton, Brian W.; Abraham, Lawrence J.; Piggott, Matthew J.
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 7 p. 1100 - 1113
反应条件
1: 2,4-dimethoxy-6-methylbenzaldehyde With 3-chloro-benzenecarboperoxoic acid in chloroform
Inert atmosphereReflux;
2: With hydrogenchloride in methanol
Inert atmosphere;
3: dimethyl sulfate With potassium carbonate in acetone
Inert atmosphere;
参考文献
Li, Jialiang; Mootoo, David R.
Synthesis (Germany), 2013 , vol. 45, # 16 art. no. SS-2013-M0314-OP, p. 2287 - 2293
