RuCl(Ph3P)3; triphenylphosphine in tetrahydrofuran; isopropyl alcohol T=25°C; 1 h;

1: in dichloromethane; water 0.25 h; Molecular sieve; 2: With 2-pentafluorophenyl-6,17dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; N-ethyl-N,N-diisopropylamine in dichloromethane; water T=20°C; 18 h; Molecular sieve; optical yield given as percent eeenantioselective reaction;

boron trifluoride diethyl etherate; sodium iodide in acetonitrile T=-10°C; 0.0166667 h;

[cmmim][Cl] T=60 - 65°C; 1.6 h;

[RhCl(η2:η2-cycloocta-1,5-diene)]2; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in 1,2-dichloro-benzene T=140°C; 14 h; Sealed tubeInert atmosphere;