6,7-二氢-5H-苯并环庚烯合成路线 （共 14 条）
反应条件
Pb3O4; acetic anhydride; acetic acid Erwaermen des Reaktionsprodukts mit wss.-aethanol. H2SO4;
参考文献
Eldin, Sherif; Pollack, Ralph M.; Whalen, Dale L.
Journal of the American Chemical Society, 1991 , vol. 113, # 4 p. 1344 - 1349
参考文献
Christol et al.
Bulletin de la Societe Chimique de France, 1959 , p. 1238,1242
反应条件
toluene-4-sulfonic acid in benzene
1 h; Heating;
参考文献
Prasad, Mohan; Rastogi, Shri Niwas
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 8 p. 753 - 757
反应条件
toluene-4-sulfonic acid; 3-hydroxy-2,2-dimethylpropanol in toluene
24 h; Reflux;
参考文献
Imai, Masao; Morais, Goreti Ribeiro; Al-Hindawi, Bassam; Al-Sulaibi, Mazen A.M.; Meetani, Mohammad; Thiemann, Thies
Journal of Chemical Research, 2010 , # 6 p. 325 - 329
反应条件
tetrachlorosilane in chloroform
T=20°C; 4.5 h;
参考文献
Firouzabadi, Habib; Iranpoor, Naser; Karimi, Babak; Hazarkhani, Hassan
Synthetic Communications, 2003 , vol. 33, # 21 p. 3671 - 3677
反应条件
sodium borohydride in methanol; water; toluene
参考文献
Aventis Pharma Deutschland GmbH
Patent: US6333349 B1, 2001 ;
US 6333349 B1
参考文献
Pomerantz,M.; Ross,A.S.
Journal of the American Chemical Society, 1975 , vol. 97, # 20 p. 5850 - 5855
反应条件
T=550°C; P=0.01 Torr; Yield given;
参考文献
Durst, Tony; Lancaster, Michael; Smith, David J. H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1846 - 1848
反应条件
1: H2O2 / acetic acid
2: 1.) BuLi / 1.) Et2O, -78 deg C -> room temperature; room temperature, 1 h, 2.) -78 deg C -> room temperature; room temperature, 2 h
3: 550 °C / 0.01 Torr
View Scheme
参考文献
Durst, Tony; Lancaster, Michael; Smith, David J. H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1846 - 1848
反应条件
1: 89 percent / Na2S, triethylhexadecylammonium chloride / CH2Cl2; H2O / 18 h / Ambient temperature; dark
2: H2O2 / acetic acid
3: 1.) BuLi / 1.) Et2O, -78 deg C -> room temperature; room temperature, 1 h, 2.) -78 deg C -> room temperature; room temperature, 2 h
4: 550 °C / 0.01 Torr
View Scheme
参考文献
Durst, Tony; Lancaster, Michael; Smith, David J. H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1846 - 1848
