1,4-二甲基-2,5-二硝基苯合成路线 （共 14 条）
反应条件
ruthenium on carbon; hydrogen T=90°C; P=11251.1 Torr;
参考文献
Hou, Jie; Ma, Yonghuan; Li, Yuhan; Guo, Fang; Lu, Lianhai
Chemistry Letters, 2008 , vol. 37, # 9 p. 974 - 975
反应条件
dihydrogen peroxide in trifluoroacetic acid
10 h; Ambient temperature;
参考文献
Rathore, R.; Kim, J. S.; Kochi, J. K.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 19 p. 2675 - 2684
参考文献
Lellmann
Justus Liebigs Annalen der Chemie, 1885 , vol. 228, p. 243
反应条件
1: 72 percent / hydroxylamine hydrochloride / ethanol / 24 h / Heating
2: 71 percent / hydroxylamine hydrochloride / ethanol / 10 h / Heating
3: 92 percent / NO2, O2 / CH2Cl2 / 4 h / Ambient temperature
4: 92 percent / 30percent H2O2 / trifluoroacetic acid / 10 h / Ambient temperature
View Scheme
参考文献
Rathore, R.; Kim, J. S.; Kochi, J. K.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 19 p. 2675 - 2684
反应条件
1: 71 percent / hydroxylamine hydrochloride / ethanol / 10 h / Heating
2: 92 percent / NO2, O2 / CH2Cl2 / 4 h / Ambient temperature
3: 92 percent / 30percent H2O2 / trifluoroacetic acid / 10 h / Ambient temperature
View Scheme
参考文献
Rathore, R.; Kim, J. S.; Kochi, J. K.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 19 p. 2675 - 2684
反应条件
1: 92 percent / NO2, O2 / CH2Cl2 / 4 h / Ambient temperature
2: 92 percent / 30percent H2O2 / trifluoroacetic acid / 10 h / Ambient temperature
View Scheme
参考文献
Rathore, R.; Kim, J. S.; Kochi, J. K.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 19 p. 2675 - 2684
反应条件
acetic anhydride; nitrogen(IV) oxide
T=20°C; 17 h; Further byproducts given;
参考文献
Abell, Andrew D.; Hartshorn, Michael P.; Maclennan, Michael E.; Robinson, Ward T.; Wright, Graeme J.
Australian Journal of Chemistry, 1991 , vol. 44, p. 43 - 51
反应条件
sodium hydrogencarbonate; copper(II) sulfate; acetic acid; sodium nitrite; isopentyl nitrite
1.) water, 25 deg C, 30 min; 2.) H2O, 60 deg C, 20 min; Yield given. Multistep reaction;
参考文献
Arya, Dev P.; Jebaratnam, David J.
Tetrahedron Letters, 1995 , vol. 36, # 25 p. 4369 - 4372
反应条件
sulfuric acid; sodium nitrite
参考文献
Staab,H.A.; Haffner,H.
Chemische Berichte, 1977 , vol. 110, p. 3358 - 3365
反应条件
acetic anhydride; nitrogen(IV) oxide
T=20°C; 17 h; other 1,4-dimethyl-4-nitrocyclohexa-2,5-dienyl acetate; other solvent; Product distributionMechanism;
参考文献
Abell, Andrew D.; Hartshorn, Michael P.; Maclennan, Michael E.; Robinson, Ward T.; Wright, Graeme J.
Australian Journal of Chemistry, 1991 , vol. 44, p. 43 - 51
