双环[3.2.0]庚-2-烯-6-酮合成路线 （共 13 条）
反应条件
With AFL619 recombinant BVMO from Aspergillus flavus NRRL3357 in methanol T=20°C; Baeyer-Villiger Ketone Oxidation; pH=8; 2 h; Enzymatic reaction; enantioselective reaction; Show Experimental Procedure
参考文献
Ferroni; Smit; Opperman Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 107, p. 47 - 54
反应条件
With sodium tetrahydroborate; hydrogen in methanol T=-78°C; 1.25 h; Inert atmosphere;
参考文献
Lentsch, Christoph; Fuerst, Rita; Mulzer, Johann; Rinner, Uwe European Journal of Organic Chemistry, 2014 , vol. 2014, # 5 p. 919 - 923
反应条件
Multi-step reaction with 4 steps 1.1: baker's yeast; sucrose / H2O / 72 h / Enzymatic reaction2.1: CrO3; H2SO4 3.1: 75 percent / MCPBA; NaHCO3 / CH2Cl2 / 25 °C4.1: H2SO4 / acetic acid4.2: 63 percent / DMAP; pyridine / CH2Cl2
参考文献
Fairlamb, Ian J.S.; Dickinson, Julia M.; O'Connor, Rachael; Higson, Seamus; Grieveson, Lynsey; Marin, Veronica Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 8 p. 2641 - 2656
