4,4',4''-(1-乙烯基-2-亚基)三苯甲醚合成路线 （共 36 条）
反应条件
lithium aluminium tetrahydride
anschliessendes Erhitzen mit wss. H3PO4;
参考文献
Sumrell; Goheen
Journal of the American Chemical Society, 1955 , vol. 77, p. 3805
反应条件
1: tetrahydrofuran / 12 h / Heating
2: 0.99 g / aq. HBr / tetrahydrofuran / 2 h / 20 °C
View Scheme
参考文献
Lubczyk, Veronika; Bachmann, Helmut; Gust, Ronald
Journal of Medicinal Chemistry, 2003 , vol. 46, # 8 p. 1484 - 1491
反应条件
1: 67 percent / AlCl3 / 1,2-dichloro-ethane / 2 h / Heating
2: tetrahydrofuran / 12 h / Heating
3: 0.99 g / aq. HBr / tetrahydrofuran / 2 h / 20 °C
View Scheme
参考文献
Lubczyk, Veronika; Bachmann, Helmut; Gust, Ronald
Journal of Medicinal Chemistry, 2003 , vol. 46, # 8 p. 1484 - 1491
反应条件
1: aqueous H2SO4
3: LiAlH4 / anschliessendes Erhitzen mit wss. H3PO4
View Scheme
参考文献
Sumrell; Goheen
Journal of the American Chemical Society, 1955 , vol. 77, p. 3805
反应条件
2: LiAlH4 / anschliessendes Erhitzen mit wss. H3PO4
View Scheme
参考文献
Sumrell; Goheen
Journal of the American Chemical Society, 1955 , vol. 77, p. 3805
反应条件
1: aqueous phosphoric acid / 100 - 120 °C / Destillieren des Reaktionsprodukts bei 0.1 Torr bzw. bei 0.2 Torr
2: LiAlH4 / anschliessendes Erhitzen mit wss. H3PO4
View Scheme
参考文献
Sumrell; Goheen
Journal of the American Chemical Society, 1955 , vol. 77, p. 3805
反应条件
titanium tetrachloride
参考文献
Sisido et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 3591
反应条件
in acetone
T=5°C; 1 h; Irradiation;
参考文献
Kitamura, Tsugio; Kobayashi, Shinjiro; Taniguchi, Hiroshi
Journal of Organic Chemistry, 1984 , vol. 49, p. 4755 - 4760
反应条件
palladium diacetate; potassium carbonate; 1-n-butyl-3-methylimidazolium tetrafluoroborate in ethanol
T=70°C; Sonogashira coupling; 72 h; Inert atmosphereSealed vessel;
参考文献
Barros, Jose C.; Souza, Andrea L. F.; Da Silva, Joaquim F. M.; Antunes
Catalysis Letters, 2011 , vol. 141, # 4 p. 549 - 553
反应条件
tetraethylammonium bromide in acetic acid
T=23°C; Irradiationvar. temp.; var. atmosphere; var. reaction conditions; other α-arylvinyl bromides; Product distributionQuantum yield;
参考文献
Van Ginkel, Frits I. M.; Cornelisse, Jan; Lodder, Gerrit
Journal of the American Chemical Society, 1991 , vol. 113, # 11 p. 4261 - 4272
