in water
Kinetics; dissociation reaction at 20°C; determination of velocity constant in presence of LiCl; mechanism discussed;;
参考文献
Nuernberg, H. W.; Duerbeck, H. W.
Zeitschrift fuer Analytische Chemie, 1964 , vol. 205, p. 217 - 237
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Gmelin Handbook: C: MVol.C4, 6.7.1.1.4, page 175 - 176
CH3COOH in tetrahydrofuran
byproducts: CO; Stirring of THF soln. of starting materials with CH3COOH (3 days, room temp., N2 or Ar).; Evolution of CO obsd. (gas chromy.), IR identification of dimer anion in soln. Filtn. of soln. affords org. compd.;
CH3COOH in gaseous matrix
Kinetics; in He at 300K; MS, not isolated;
参考文献
Gronert, Scott; O'Hair, Richard A. J.; Prodnuk, Stephen; Suelzle, Detlev; Damrauer, Robert; DePuy, Charles H.
Journal of the American Chemical Society, 1990 , vol. 112, p. 998 - 1003
macrocyclic polyaminelt;24gt;-N6O2 in water
T=40°C; pH=7, further pH-s, further temperatures, further catalysts, effect of anions (AMP2-, SO42-, C2O42-, HPO42-) on rate constans; MechanismRate constant;
参考文献
Hosseini,M.W.; Lehn,J.M.
Journal of the American Chemical Society, 1987 , vol. 109, p. 7047
