oxygen; copper dichloride in hydrogenchloride byproducts: n-PrCl, H2O; reaction of red phosphorus with a mixt. of alcohol, CuCl2, HCl and oxygen under argon; the trialkyl phosphate is isolated after removal of the low-boiling fractions by distn. in vac., gas-liquid chromy.;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 61, p. 999 - 1008
Zhurnal Obshchei Khimii, , vol. 61, p. 1101 - 1110
O2; CuCl2 in neat (no solvent) Kinetics; byproducts: H2O, HCl; the alcohol was loaded together with CuCl2 into the reactor and purged with an Ar-O2 mixture; the Cu3P was added and the mixt. reacted at 293 K, 323 K, or 343 K;;
参考文献
Kinetics and Catalysis, , vol. 33, p. 243 - 251
Kinetika i Kataliz, , vol. 33, p. 304 - 313
O2; CuCl2; LiCl in neat (no solvent) Kinetics; byproducts: H2O, HCl; the alcohol was loaded together with CuCl2 into the reactor and purged with an Ar-O2 mixture; then Cu3P was added and the mixt reacted in the presence of LiCl at 323 K;;
参考文献
Kinetics and Catalysis, , vol. 33, p. 243 - 251
Kinetika i Kataliz, , vol. 33, p. 304 - 313
