4-(三氟甲基亚磺酰基)氯苯合成路线 （共 7 条）
反应条件
[bmim]BF4; trichloroisocyanuric acid; water
T=20°C; 1 h;
参考文献
Tang, Ri-Yuan; Zhong, Ping; Lin, Qiu-Lian
Journal of Fluorine Chemistry, 2007 , vol. 128, # 6 p. 636 - 640
参考文献
Rhodia Chimie
Patent: US6486351 B1, 2002 ;
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran
30 min at -25 deg C, then slowly warmed up to 10 deg C (total time 2 h);
参考文献
Movchun, Valeria N.; Kolomeitsev, Alexander A.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 1995 , vol. 70, # 2 p. 255 - 258
反应条件
1: 83 percent / Na2HPO4; Na2S2O4 / dimethylformamide; H2O / 2.5 h / 20 °C / 9000.9 Torr
2: 98 percent / trichloroisocyanuric acid; [Bmim]BF4; H2O / 1 h / 20 °C
View Scheme
参考文献
Tang, Ri-Yuan; Zhong, Ping; Lin, Qiu-Lian
Journal of Fluorine Chemistry, 2007 , vol. 128, # 6 p. 636 - 640
反应条件
trifluoromethylsulfonic anhydride
T=20°C; Title compound not separated from byproducts;
参考文献
Wakselman; Tordeux; Freslon; Saint-Jalmes
Synlett, 2001 , # 4 p. 550 - 552
反应条件
1: SnCl2, aq. HCl / methanol
2: (i) aq. HCl, NaNO2, (ii) aq. HCl, Na2S2O3
View Scheme
参考文献
Yagupol'skii,L.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 2 p. 377 - 387,377 - 385
反应条件
(i) aq. HCl, NaNO2, (ii) aq. HCl, Na2S2O3; Multistep reaction;
参考文献
Yagupol'skii,L.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 2 p. 377 - 387,377 - 385
