4-羟基-2,6-二甲基苯甲酸甲酯合成路线 （共 4 条）
反应条件
sodium dithionite; sodium hydroxide in ethanol; water
T=20°C; 0.666667 h; Inert atmosphere;
参考文献
Zhao, Wenjun; Huang, Li; Guan, Yong; Wulff, William D.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 13 p. 3436 - 3441
Angew. Chem., 2014 , vol. 126, # 13 p. 3504 - 3509,6
反应条件
acetic acid; sodium nitrite
T=10 - 15°C; anschliessendes Erwaermen auf 90grad;
参考文献
Merck,E.
Patent: DE736797 , 1940 ;
DRP/DRBP Org.Chem.
反应条件
1: sodium dithionite / methanol; water; diethyl ether / 1 h / 20 °C / |Inert atmosphere
2: sulfuric acid / 1.7 h / 20 °C / |Inert atmosphere
3: sodium dithionite; sodium hydroxide / water; ethanol / 0.67 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Zhao, Wenjun; Huang, Li; Guan, Yong; Wulff, William D.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 13 p. 3436 - 3441
Angew. Chem., 2014 , vol. 126, # 13 p. 3504 - 3509,6
反应条件
1: sulfuric acid / 1.7 h / 20 °C / |Inert atmosphere
2: sodium dithionite; sodium hydroxide / water; ethanol / 0.67 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Zhao, Wenjun; Huang, Li; Guan, Yong; Wulff, William D.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 13 p. 3436 - 3441
Angew. Chem., 2014 , vol. 126, # 13 p. 3504 - 3509,6
