3-羟基-4-硝基苯甲醛合成路线 （共 21 条）
反应条件
CuCl2·2H2O; water in acetonitrile T=75°C; 2 h;
参考文献
Quan, Na; Shi, Xiao-Xin; Nie, Liang-Deng; Dong, Jing; Zhu, Rui-Heng
Synlett, 2011 , # 7 p. 1028 - 1032
反应条件
manganese(IV) oxide in dichloromethane 20 h;
参考文献
Olszewski; Marshalla; Sabat; Sundberg
Journal of Organic Chemistry, 1994 , vol. 59, # 15 p. 4285 - 4296
反应条件
nitric acid; potassium bromide in acetic anhydride T=20°C;
参考文献
Tetrahedron Letters, , vol. 50, # 7 p. 831 - 833
反应条件
1: 87 percent / 10 M BH3*SMe2 / tetrahydrofuran / 3 h / Heating 2: 100 percent / MnO2 / CH2Cl2 / 20 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 59, # 15 p. 4285 - 4296
参考文献
Chemische Berichte, , vol. 62, p. 1182
Chemische Berichte, , vol. 66, p. 1761,1762
Journal of the Chemical Society, , vol. 127, p. 876,877
Journal of the Chemical Society, , p. 150
参考文献
DE18016 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 1, p. 586,587
DE20116 ;
Chemische Berichte, , vol. 22, p. 2341
Chemische Berichte, , vol. 15, p. 2053,3052
反应条件
1: potassium carbonate / N,N-dimethyl-formamide / 1 h / 60 °C 2: iron; ammonium chloride / ethanol; water / 2 h / 78 °C 3: n-Butyl nitrite; copper(I) bromide / acetonitrile / 18 h / 20 °C View Scheme
参考文献
MSD OSS B.V.; BLACKABY, Wesley, Peter; DE KORT, Martin; ENTHOVEN, Mark; HINCHLIFFE, Paul, Stuart; PAULIE, Chris; TIMMERS, Cornelis, Marius; VERKAIK, Saskia
Patent: WO2013/41458 A1, 2013 ;
反应条件
1: Ac2O / Heating 2: quinoline, copper chromite / 220 °C 3: I2 / nitrobenzene / Heating 4: N2H4*H2O / Raney-Ni / ethanol 5: Py 6: aq. NH3 / ethyl acetate View Scheme
参考文献
Metzler,M.; Neumann,H.-G.
Tetrahedron, 1971 , vol. 27, p. 2225 - 2246
反应条件
1: 97 percent / NaBH4 / methanol; tetrahydrofuran; diethyl ether / 0 deg C, 30 min, 0 deg C to rt, 2 h 2: 86 percent / CBr4, PPh3 / CH2Cl2 / 0 deg C, 30 min, 0 deg C to rt View Scheme
参考文献
La Clair, James J.
Journal of the American Chemical Society, 1997 , vol. 119, # 33 p. 7676 - 7684
反应条件
sodium tetrahydroborate in tetrahydrofuran; methanol; diethyl ether 0 deg C, 30 min, 0 deg C to rt, 2 h;
参考文献
La Clair, James J.
Journal of the American Chemical Society, 1997 , vol. 119, # 33 p. 7676 - 7684
