2,2-二氟-1-苯基-1-丙酮合成路线 （共 14 条）
反应条件
4 A molecular sieve; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in acetonitrile
T=-10°C;
参考文献
Peng, Weimin; Shreeve, Jean'ne M.
Journal of Organic Chemistry, 2005 , vol. 70, # 14 p. 5760 - 5763
反应条件
1: With N-butylamine; trifluoroacetic acid in benzene
RefluxInert atmosphere;
2: With 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in acetonitrile
RefluxInert atmosphere;
3: With hydrogenchloride in water
参考文献
Bergeron, Maxime; Johnson, Thomas; Paquin, Jean-Francois
Angewandte Chemie - International Edition, 2011 , vol. 50, # 47 p. 11112 - 11116
反应条件
water; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in acetonitrile
Heating;
参考文献
Zupan, Marko; Iskra, Jernej; Stavber, Stojan
Journal of Organic Chemistry, 1995 , vol. 60, # 1 p. 259 - 260
反应条件
methanol; CsSO4F
1 h; Ambient temperature; Further byproducts given;
参考文献
Stavber, Stojan; Zupan, Marko
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 5022 - 5025
反应条件
mercury(II) fluoride
参考文献
Modarai,B.; Khoshdel,E.
Journal of Organic Chemistry, 1977 , vol. 42, # 22 p. 3527 - 3531
参考文献
Merritt,R.F.
Journal of Organic Chemistry, 1967 , vol. 32, p. 4124 - 4126
反应条件
methanol; CsSO4F
1 h; Ambient temperature; Further byproducts given. Title compound not separated from byproducts;
参考文献
Stavber, Stojan; Zupan, Marko
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 5022 - 5025
反应条件
methanol; CsSO4F
1 h; Ambient temperature; Further byproducts given;
参考文献
Stavber, Stojan; Zupan, Marko
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 5022 - 5025
反应条件
CsSO4F
1 h; Ambient temperature; Further byproducts given. Title compound not separated from byproducts;
参考文献
Stavber, Stojan; Zupan, Marko
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 5022 - 5025
反应条件
CsSO4F
1 h; Ambient temperature; Further byproducts given;
参考文献
Stavber, Stojan; Zupan, Marko
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 5022 - 5025
