Nikolaeva, S. N.; Zolotareva, A. S.; Ponomarev, S. V.; Petrosyan, V. S.
Russian Chemical Bulletin, 1994 , vol. 43, # 5 p. 857 - 861
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1994 , # 5 p. 911 - 915
methanol; triethylamine in pentane byproducts: bromotrimethylgermane; argon atmosphere; B-compd. soln. addn. to Ge-compd. soln. (stirring); B-compd. isolation on solvent and bromotrimethylgermane driving off; elem. anal.;
参考文献
Ponomarev, S. V.; Nikolaeva, S. N.; Molchanova, G. N.; Kostyuk, A. S.; Grishin, Yu. K.
Journal of General Chemistry USSR (English Translation), 1984 , vol. 54, p. 1620 - 1623
Zhurnal Obshchei Khimii, 1984 , vol. 54, p. 1817 - 1821
→
反应条件
in pentane Ar atmosphere; dropwise addn. of soln. of borane to soln. of ester (-10°C); fractionation; elem. anal.;
参考文献
Nikolaeva, S. N.; Zolotareva, A. S.; Ponomarev, S. V.; Grishin, Yu. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1489 - 1490
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1674 - 1675
in pentane Ar atmosphere; dropwise addn. of soln. of borane to soln. of ester (-20°C); fractionation; elem. anal.;
参考文献
Nikolaeva, S. N.; Zolotareva, A. S.; Ponomarev, S. V.; Grishin, Yu. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1489 - 1490
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1674 - 1675
in pentane Ar atmosphere; dropwise addn. of soln. of borane to soln. of ester (-10°C); fractionation; elem. anal.;
参考文献
Nikolaeva, S. N.; Zolotareva, A. S.; Ponomarev, S. V.; Grishin, Yu. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1489 - 1490
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1674 - 1675
in pentane to a soln. of (CH3)3GeCH((C4H9)3Sn)COOCH3 in dry pentane is added with stirring and cooling (-30°C) a soln. of BrB(N(CH3)2 dropwise under Ar; evapn. (only Z-isomer is detected by IR and NMR), fractionation yields mixt. of isomers, residue is bromotributyl stannane;
参考文献
Nikolaeva, S. N.; Zolotareva, A. S.; Ponomarev, S. V.; Petrosyan, V. S.
Journal of General Chemistry USSR (English Translation), 1991 , vol. 61, p. 837 - 840
Zhurnal Obshchei Khimii, 1991 , vol. 61, p. 921 - 925
in pentane to a soln. of ((CH3)3Ge)2CHCOOCH3 in dry pentane is added a soln. of ((CH3)2N)2BBr in dry pentane dropwise; the react. mixt. is stirred for 15 min. (under Ar); fractionation with a trap; elem. anal.;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 61, p. 837 - 840
Zhurnal Obshchei Khimii, , vol. 61, p. 921 - 925
Nikolaeva, S. N.; Zolotareva, A. S.; Ponomarev, S. V.; Grishin, Yu. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1489 - 1490
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1674 - 1675
