1-乙基-1,2,5,6-四氢吡啶合成路线 （共 9 条）
反应条件
3,4-dihydroxy-1-tert-butylbenzene
T=485°C;
参考文献
Leonard; Gash
Journal of the American Chemical Society, 1954 , vol. 76, p. 2781,2784
反应条件
1: Raney nickel; ethanol / 150 °C / 66195.7 Torr / Hydrogenation
2: toluene; hydrogen chloride / anschliessenden Erwaermen mit Thionylchlorid
3: potassium hydroxide / 180 °C
View Scheme
参考文献
Paul; Tchelitcheff
Bulletin de la Societe Chimique de France, 1954 , p. 982,984
反应条件
1: toluene; hydrogen chloride / anschliessenden Erwaermen mit Thionylchlorid
2: potassium hydroxide / 180 °C
View Scheme
参考文献
Paul; Tchelitcheff
Bulletin de la Societe Chimique de France, 1954 , p. 982,984
反应条件
sodium tetrahydroborate in ethanol
T=0°C;
参考文献
Grishina; Borisenko; Nosan'; Veselov; Ashkinadze; Karamov; Kornilaeva; Zefirov
Doklady Chemistry, 2003 , vol. 391, # 4-6 p. 195 - 199
反应条件
1: 74 percent / K2CO3 / acetone / 24 h
2: 84 percent / ethanol / 2 h / Heating
3: 83 percent / Bu3SnH; AIBN / toluene / 3 h / Heating
View Scheme
参考文献
Della, Ernest W.; Smith, Paul A.
Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6627 - 6633
反应条件
1: 84 percent / ethanol / 2 h / Heating
2: 83 percent / Bu3SnH; AIBN / toluene / 3 h / Heating
View Scheme
参考文献
Della, Ernest W.; Smith, Paul A.
Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6627 - 6633
反应条件
potassium carbonate in acetone
Alkylation; 24 h;
参考文献
Della, Ernest W.; Smith, Paul A.
Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6627 - 6633
反应条件
potassium hydroxide
T=180°C;
参考文献
Paul; Tchelitcheff
Bulletin de la Societe Chimique de France, 1954 , p. 982,984
反应条件
Erhitzen des Reaktionsgemisches mit Ameisensaeure und Kaliumformiat;
参考文献
Kost et al.
Vestnik Moskovk. Univ.Chem.Abstr., 1956 , vol. 11, # 1 p. 209,211
Vestnik Moskovk. Univ.Chem.Abstr., 1958 , p. 9114
