2-溴-1-(4-羟基-3-甲氧基苯基)乙酮合成路线 （共 13 条）
反应条件
1: DBU / dioxane / 12 h / 0 - 20 °C 2: TFA / 4 h / 0 °C 3: H2O / UV-irradiation View Scheme
参考文献
Conrad II, Peter G.; Givens, Richard S.; Weber, Joerg F. W.; Kandler, Karl
Organic Letters, 2000 , vol. 2, # 11 p. 1545 - 1547
反应条件
1: DBU / dioxane / 12 h / 0 - 20 °C 2: TFA / 4 h / 0 °C 3: H2O / UV-irradiation View Scheme
参考文献
Conrad II, Peter G.; Givens, Richard S.; Weber, Joerg F. W.; Kandler, Karl
Organic Letters, 2000 , vol. 2, # 11 p. 1545 - 1547
反应条件
1: 2-methoxy-phenol With sodium in ethanol 2: α-bromo-3-methoxy-4-hydroxyacetophenone in N,N-dimethyl-formamide Cooling with ice;
参考文献
Song, Qi; Wang, Feng; Xu, Jie
Chemical Communications, 2012 , vol. 48, # 56 p. 7019 - 7021
反应条件
1: DBU / dioxane / 12 h / 0 - 20 °C 2: TFA / 4 h / 0 °C 3: H2O / UV-irradiation View Scheme
参考文献
Conrad II, Peter G.; Givens, Richard S.; Weber, Joerg F. W.; Kandler, Karl
Organic Letters, 2000 , vol. 2, # 11 p. 1545 - 1547
反应条件
1.1: sodium / ethanol 1.2: Cooling with ice 2.1: potassium carbonate / ethanol / 2 h / 49.84 °C 3.1: sodium tetrahydroborate; sodium hydroxide / 20 °C 4.1: ; hydrogen / ethylene glycol / 199.84 °C / 37503.8 Torr / Autoclave View Scheme
参考文献
Song, Qi; Wang, Feng; Xu, Jie
Chemical Communications, 2012 , vol. 48, # 56 p. 7019 - 7021
反应条件
1.1: sodium / ethanol 1.2: Cooling with ice 2.1: potassium carbonate / ethanol / 2 h / 49.84 °C 3.1: sodium tetrahydroborate; sodium hydroxide / 20 °C 4.1: 10 palladium on activated charcoal; hydrogen / ethylene glycol / 199.84 °C / 37503.8 Torr / Autoclave View Scheme
参考文献
Song, Qi; Wang, Feng; Xu, Jie
Chemical Communications, 2012 , vol. 48, # 56 p. 7019 - 7021
反应条件
1.1: sodium / ethanol 1.2: Cooling with ice 2.1: potassium carbonate / ethanol / 2 h / 49.84 °C 3.1: sodium tetrahydroborate; sodium hydroxide / 20 °C 4.1: ; hydrogen / ethylene glycol / 199.84 °C / 37503.8 Torr / Autoclave View Scheme
参考文献
Song, Qi; Wang, Feng; Xu, Jie
Chemical Communications, 2012 , vol. 48, # 56 p. 7019 - 7021
反应条件
1.1: sodium / ethanol 1.2: Cooling with ice 2.1: potassium carbonate / ethanol / 2 h / 49.84 °C 3.1: sodium tetrahydroborate; sodium hydroxide / 20 °C View Scheme
参考文献
Song, Qi; Wang, Feng; Xu, Jie
Chemical Communications, 2012 , vol. 48, # 56 p. 7019 - 7021
反应条件
bromine in 1,4-dioxane; diethyl ether
T=0°C; 1 h;
参考文献
Kishimoto, Takao; Uraki, Yasumitsu; Ubukata, Makoto
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 6 p. 1067 - 1073
反应条件
carbon disulfide; aluminium trichloride
参考文献
Riegel; Wittcoff
Journal of the American Chemical Society, 1946 , vol. 68, p. 1913,1916
