双环[2.2.1]庚-5-烯-2-酮合成路线 (共 39 条)
反应条件
potassium hydroxide in water; dimethyl sulfoxide 48 h; Ambient temperature;
参考文献
Drian, Claude Le; Greene, Andrew E.
Journal of the American Chemical Society, 1982 , vol. 104, # 20 p. 5473 - 5483
反应条件
dipyridinium dichromate; pyridinium trifluoroacetate in dichloromethane 6 h; Ambient temperature;
参考文献
Saunders, Martin; Jarret, Ronald M.; Pramanik, Pradip
Journal of the American Chemical Society, 1987 , vol. 109, # 12 p. 3735 - 3739
反应条件
Sarett’s reagent in dichloromethane 2 h; Ambient temperature;
参考文献
Fischer, Walter; Grob, Cyril A.; Sprecher, Georg von; Waldner, Adrian
Helvetica Chimica Acta, 1980 , vol. 63, # 4 p. 816 - 823
反应条件
triethylamine in dichloromethane; water; dimethyl sulfoxide
反应条件
LiNMe2 in tetrahydrofuran T=-78°C; 1 h; -78 deg C to r.t.;
参考文献
Baumgaertel, Otto; Szeimies, Guenter
Chemische Berichte, 1983 , vol. 116, # 6 p. 2180 - 2204
反应条件
1: benzene / Heating 2: H2O/HCl View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 24 p. 1872 - 1873
反应条件
sulfuric acid 6 h; Heating;
参考文献
Minuti; Taticchi; Marrocchi; Costantini; Wenkert
Synthetic Communications, 2001 , vol. 31, # 5 p. 707 - 710
反应条件
1.1: Hg(OAc)2 / tetrahydrofuran / 12 h / 20 °C 1.2: 1.63 g / sodium amalgam; aq. NaOH / 18 h 2.1: 48 percent / CrO3; pyridine / CH2Cl2 / 48 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 66, # 15 p. 5182 - 5191
反应条件
1: 75 percent / sodium amalgam; NaOH / 18 h / 20 °C 2: 48 percent / CrO3; pyridine / CH2Cl2 / 48 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 58, # 47 p. 9513 - 9525
反应条件
1: 27 percent / CuF2*2H2O 2: 56 percent / MCPBA / dimethylformamide / 1 h / -50 °C View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 254, # 1 p. 13 - 22