1,1-二氟-2-乙烯基环丙烷合成路线 （共 11 条）
反应条件
in 2-methyl-butane; cyclohexane T=203.1 - 267°C; Ea, ΔH*, ΔS*; KineticsThermodynamic data;
参考文献
Roth, Wolfgang R.; Kirmse, Wolfgang; Hoffmann, Wilfried; Lennartz, Hans-Werner
Chemische Berichte, 1982 , vol. 115, # 7 p. 2508 - 2515
反应条件
T=210°C; energy of activation, Ea; Thermodynamic data;
参考文献
Dolbier, William R.; Al-Pekri, Dheya M.
Tetrahedron, 1987 , vol. 43, # 1 p. 39 - 44
反应条件
potassium permanganate in water 36 h;
参考文献
Gassen, K. R.; Baasner, B.
Journal of Fluorine Chemistry, 1990 , vol. 49, # 1 p. 127 - 139
反应条件
tetrabutylammomium bromide; hydroquinone in various solvent(s)
T=120°C; P=15001.2 Torr;
参考文献
Gassen, K. R.; Baasner, B.
Journal of Fluorine Chemistry, 1990 , vol. 49, # 1 p. 127 - 139
反应条件
potassium fluoride in various solvent(s)
24 h; Yield given;
参考文献
Dolbier,W.R.; Sellers,S.F.
Journal of the American Chemical Society, 1982 , vol. 104, p. 2494
反应条件
zinc; iodine in tetrahydrofuran
Ambient temperature;
参考文献
Dolbier, William R.; Wojtowicz, Hanna; Burkholder, Conrad R.
Journal of Organic Chemistry, 1990 , vol. 55, # 19 p. 5420 - 5422
参考文献
Mitsch,R.A.
Journal of the American Chemical Society, 1965 , vol. 87, p. 758 - 761
参考文献
Sargeant,P.B.
Journal of Organic Chemistry, 1970 , vol. 35, p. 678 - 682
反应条件
1.) ether, 20 h, RT, 2.) 289 deg C, 0.25-0.4 Torr, 80 min; the two 34 and 38 and 39 not separated; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Dolbier, William R.; Al-Pekri, Dheya M.
Tetrahedron, 1987 , vol. 43, # 1 p. 39 - 44
反应条件
multistep reaction; Mechanism;
参考文献
Dolbier, William R.; Al-Pekri, Dheya M.
Tetrahedron, 1987 , vol. 43, # 1 p. 39 - 44
