3,4-二氢化-5-甲基-1(2H)-萘酮合成路线 （共 40 条）
反应条件
in benzene
T=295 - 340°C;
参考文献
Munslow, William D.; Reusch, William
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5096 - 5099
反应条件
1: AlCl3 / 70 °C
2: ZnCl2, HCl / 70 °C
3: NaOEt / ethanol
4: (hydrolysis)
5: 150 °C
6: (i) LiAlH4, Et2O (ii) HBr, H2SO4, AcOH
7: aq. ethanol
8: K2CO3 / aq. ethanol / 48 h / Heating
9: polyphosphoric acid / 1 h / 90 - 100 °C
View Scheme
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
1: ZnCl2, HCl / 70 °C
2: NaOEt / ethanol
3: (hydrolysis)
4: 150 °C
5: (i) LiAlH4, Et2O (ii) HBr, H2SO4, AcOH
6: aq. ethanol
7: K2CO3 / aq. ethanol / 48 h / Heating
8: polyphosphoric acid / 1 h / 90 - 100 °C
View Scheme
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
1: ZnCl2, HCl
2: NaOEt / ethanol
3: (hydrolysis)
4: 150 °C
5: (i) LiAlH4, Et2O (ii) HBr, H2SO4, AcOH
6: aq. ethanol
7: K2CO3 / aq. ethanol / 48 h / Heating
8: polyphosphoric acid / 1 h / 90 - 100 °C
View Scheme
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
PPA
T=90 - 100°C; 1 h;
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
PPA
T=90 - 100°C; 1 h;
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
1: NaOEt / ethanol
2: (hydrolysis)
3: 150 °C
4: (i) LiAlH4, Et2O (ii) HBr, H2SO4, AcOH
5: aq. ethanol
6: K2CO3 / aq. ethanol / 48 h / Heating
7: polyphosphoric acid / 1 h / 90 - 100 °C
View Scheme
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
1: aq. ethanol
2: K2CO3 / aq. ethanol / 48 h / Heating
3: polyphosphoric acid / 1 h / 90 - 100 °C
View Scheme
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
1: aq. ethanol
2: K2CO3 / aq. ethanol / 48 h / Heating
3: polyphosphoric acid / 1 h / 90 - 100 °C
View Scheme
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
反应条件
1: NaOEt / ethanol
2: (hydrolysis)
3: 150 °C
4: (i) LiAlH4, Et2O (ii) HBr, H2SO4, AcOH
5: aq. ethanol
6: K2CO3 / aq. ethanol / 48 h / Heating
7: polyphosphoric acid / 1 h / 90 - 100 °C
View Scheme
参考文献
Cagniant,P. et al.
Bulletin de la Societe Chimique de France, 1969 , p. 985 - 991
