alpha-甲基-gamma-氧代-苯丁酸乙酯合成路线 （共 16 条）
反应条件
sulfuric acid in ethanol
T=65°C; 72 h;
参考文献
Sato, Tsuneo; Okazaki, Hiroshi; Otera, Junzo; Nozaki, Hitosi
Journal of the American Chemical Society, 1988 , vol. 110, # 15 p. 5209 - 5211
反应条件
2,2'-azo-bisisobutyronitrile in benzene
T=80°C; 4 h;
参考文献
Miura, Katsukiyo; Fujisawa, Naoki; Saito, Hiroshi; Wang, Di; Hosomi, Akira
Organic Letters, 2001 , vol. 3, # 16 p. 2591 - 2594
反应条件
tert.-butylhydroperoxide; triethylamine; cobalt(II) 2,4-pentanedionate in water
T=100°C; 24 h; Sealed tube;
参考文献
Zhang, Feng; Du, Peng; Chen, Jijun; Wang, Hongxiang; Luo, Qiang; Wan, Xiaobing
Organic Letters, 2014 , vol. 16, # 7 p. 1932 - 1935
反应条件
chloro-trimethyl-silane in dichloromethane
T=0°C; 0.5 h;
参考文献
Hilgenkamp, Ramona; Zercher, Charles K.
Organic Letters, 2001 , vol. 3, # 19 p. 3037 - 3040
反应条件
2,4,6-trimethyl-pyridine; 2,2'-azo-bisisobutyronitrile in benzene
T=85°C; 3 h;
参考文献
Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529
反应条件
[ReCl(N2)(PMe2Ph)4] in N,N-dimethyl-formamide
Addition; Heating;
参考文献
Koga, Yuji; Kusama, Hiroyuki; Narasaka, Koichi
Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 2 p. 475 - 482
反应条件
1: 2) t-BuOK / 1) THF, 50 deg C, 14 h; 2) THF, -78 deg C, 1 h
2: 74 percent / concentrated H2SO4 / aq. ethanol / 72 h / 65 °C
View Scheme
参考文献
Sato, Tsuneo; Okazaki, Hiroshi; Otera, Junzo; Nozaki, Hitosi
Journal of the American Chemical Society, 1988 , vol. 110, # 15 p. 5209 - 5211
反应条件
bis-triphenylphosphine-palladium(II) chloride in chloroform
T=70°C; 15 h;
参考文献
Fujimura, Tsutomu; Aoki, Satoshi; Nakamura, Eiichi
Journal of Organic Chemistry, 1991 , vol. 56, # 8 p. 2809 - 2821
反应条件
hexamethyl-distannane in benzene
5 h; UV-irradiation;
参考文献
Lee, Jin Young; Lim, Kyoung-Chan; Meng, Xiangjian; Kim, Sunggak
Synlett, 2010 , # 11 p. 1647 - 1650
反应条件
1.1: iodine; mercuric oxide / diethyl ether / 3 h / 20 °C
1.2: 76 percent / t-BuOK / diethyl ether; tetrahydrofuran / 20 °C
2.1: 86 percent / AIBN; 2,4,6-collidine / benzene / 3 h / 85 °C
View Scheme
参考文献
Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529
