in neat (no solvent) decompn. at above 0°C; complete decompn. at 120°C;;

in benzene byproducts: NH4Cl;

in neat (no solvent) byproducts: NH4Cl; SiCl4 is reacted with excess NH3 at -85 °C;; excess NH3 is removed by distn. at -50 to -20 °C; no formation of Si(NH2)4 observed;;

water in water