反式-4,4-二甲基-2-戊烯合成路线 (共 28 条)
参考文献
Zhurnal Obshchei Khimii, , vol. 5, p. 1861
Chem. Zentralbl., , vol. 107, # I p. 3818
反应条件
bromine; 2-methyl cyclohexane T=-70°C; Behandeln der Reaktionsloesung mit Natriumamid in fluessigem Ammoniak;
参考文献
Miller et al.
Journal of Organic Chemistry, 1954 , vol. 19, p. 1882,1885,1887
反应条件
methanol; sodium hydroxide; dihydrogen peroxide; (-)-Monoisopinocampheylborane 1.) THF, -25 deg C, 48 h, 2.) 55 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brown, Herbert C.; Jadhav, Prabhakar K.; Mandal, Arun K.
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5074 - 5083
反应条件
in diethyl ether
T=22°C; P=2585.7 Torr; 3 h; Yield given. Yields of byproduct given;
参考文献
Rocklage,S.M.; Fellmann,J.D.; Rupprecht,G.
Journal of the American Chemical Society, 1981 , vol. 103, p. 1440
反应条件
Ta(CHCMe3)2(Me)(PMe3)2
T=25°C; P=1551.4 - 2585.7 Torr; 48 h; Yield given. Yields of byproduct given;
参考文献
Fellmann,J.D.; Schrock,R.R.; Rupprecht,G.
Journal of the American Chemical Society, 1981 , vol. 103, p. 5752
反应条件
aluminium trichloride in chlorobenzene
2 h;
参考文献
Wengrovius,J.; Schrock,R.R.; Churchill,M.
Journal of the American Chemical Society, 1980 , vol. 102, p. 4515
反应条件
1: sodium borate; diethyl ether
3: potassium acetate; acetic acid anhydride; acetic acid
View Scheme
参考文献
Brown; Nakagawa
Journal of the American Chemical Society, 1955 , vol. 77, p. 3610,3613
反应条件
WH(η5-C5HMe4)(CO3) in benzene-d6
T=140°C; 48 h;
参考文献
Chahboun, Ghaita; Petrisor, Cristina E.; Gomez-Bengoa, Enrique; Royo, Eva; Cuenca, Tomas
European Journal of Inorganic Chemistry, 2009 , # 11 p. 1514 - 1520
反应条件
2: potassium acetate; acetic acid anhydride; acetic acid
View Scheme
参考文献
Brown; Nakagawa
Journal of the American Chemical Society, 1955 , vol. 77, p. 3610,3613
反应条件
potassium acetate; acetic anhydride; acetic acid
参考文献
Brown; Nakagawa
Journal of the American Chemical Society, 1955 , vol. 77, p. 3610,3613