1,2-dichloro-ethane; manganese (II) chloride in tetrahydrofuran T=25°C; 12 h; Inert atmosphere;

sulfuryl dichloride

lithium chloride; PEPPSI-IPr catalyst in tetrahydrofuran; ethylene glycol dimethyl ether T=20°C; Kumada Coupling Reaction; 1 h; Product distribution / selectivity;