1,4-二氧杂-螺[4,5]癸-7-烯-8-硼酸频哪醇酯合成路线 （共 10 条）
反应条件
potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in 1,4-dioxane T=80°C; Inert atmosphere;
参考文献
US2010/56576 A1, ;
Page/Page column 20 ;
US 20100056576 A1
反应条件
triphenyl-arsane; triethylamine; bis-triphenylphosphine-palladium(II) chloride in toluene T=80°C; 2 h;
参考文献
US2006/3997 A1, ;
Page/Page column 7 ;
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / 1,4-dioxane; water / 24 h / 100 °C / Inert atmosphere 2: palladium 10 on activated carbon; hydrogen / methanol / 2 h / 20 °C / 2585.81 Torr 3: hydrogenchloride / acetone / 4 h / 20 °C View Scheme
参考文献
Zhang, Xuqing; Hufnagel, Heather; Markotan, Thomas; Lanter, James; Cai, Chaozhong; Hou, Cuifen; Singer, Monica; Opas, Evan; McKenney, Sandra; Crysler, Carl; Johnson, Dana; Sui, Zhihua
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 18 p. 5577 - 5582
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / 1,4-dioxane; water / 24 h / 100 °C / Inert atmosphere 2: palladium 10 on activated carbon; hydrogen / methanol / 2 h / 20 °C / 2585.81 Torr View Scheme
参考文献
Zhang, Xuqing; Hufnagel, Heather; Markotan, Thomas; Lanter, James; Cai, Chaozhong; Hou, Cuifen; Singer, Monica; Opas, Evan; McKenney, Sandra; Crysler, Carl; Johnson, Dana; Sui, Zhihua
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 18 p. 5577 - 5582
反应条件
sodium periodate; ammonium acetate in water; acetone 48 h;
参考文献
Patil, Aditi S.; Mo, Dong-Liang; Wang, Heng-Yen; Mueller, Daniel S.; Anderson, Laura L.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 31 p. 7799 - 7803
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / 1,4-dioxane; water / 24 h / 100 °C / Inert atmosphere 2: palladium 10 on activated carbon; hydrogen / methanol / 2 h / 20 °C / 2585.81 Torr 3: hydrogenchloride / acetone / 4 h / 20 °C View Scheme
参考文献
Zhang, Xuqing; Hufnagel, Heather; Markotan, Thomas; Lanter, James; Cai, Chaozhong; Hou, Cuifen; Singer, Monica; Opas, Evan; McKenney, Sandra; Crysler, Carl; Johnson, Dana; Sui, Zhihua
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 18 p. 5577 - 5582
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / 1,4-dioxane; water / 24 h / 100 °C / Inert atmosphere 2: palladium 10 on activated carbon; hydrogen / methanol / 2 h / 20 °C / 2585.81 Torr 3: hydrogenchloride / acetone / 4 h / 20 °C View Scheme
参考文献
Zhang, Xuqing; Hufnagel, Heather; Markotan, Thomas; Lanter, James; Cai, Chaozhong; Hou, Cuifen; Singer, Monica; Opas, Evan; McKenney, Sandra; Crysler, Carl; Johnson, Dana; Sui, Zhihua
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 18 p. 5577 - 5582
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in 1,4-dioxane; water T=100°C; Suzuki coupling; 24 h; Inert atmosphere;
参考文献
Zhang, Xuqing; Hufnagel, Heather; Markotan, Thomas; Lanter, James; Cai, Chaozhong; Hou, Cuifen; Singer, Monica; Opas, Evan; McKenney, Sandra; Crysler, Carl; Johnson, Dana; Sui, Zhihua
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 18 p. 5577 - 5582
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in 1,4-dioxane; water
T=100°C; Suzuki coupling; 24 h; Inert atmosphere;
参考文献
Zhang, Xuqing; Hufnagel, Heather; Markotan, Thomas; Lanter, James; Cai, Chaozhong; Hou, Cuifen; Singer, Monica; Opas, Evan; McKenney, Sandra; Crysler, Carl; Johnson, Dana; Sui, Zhihua
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 18 p. 5577 - 5582
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / 1,4-dioxane; water / 24 h / 100 °C / Inert atmosphere
2: 5 Pd(II)/C(eggshell); hydrogen / methanol / 2 h / 20 °C / 2068.65 Torr
3: hydrogenchloride / acetone / 4 h / 20 °C
View Scheme
参考文献
Zhang, Xuqing; Hufnagel, Heather; Markotan, Thomas; Lanter, James; Cai, Chaozhong; Hou, Cuifen; Singer, Monica; Opas, Evan; McKenney, Sandra; Crysler, Carl; Johnson, Dana; Sui, Zhihua
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 18 p. 5577 - 5582
