反式-BETA-苯乙烯硼酸合成路线 (共 109 条)
反应条件
1: With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tBuCH2CH2B(H)NiPr2; triethylamine; triphenylphosphine in tetrahydrofuran T=65°C; Alcaraz-Vaultier borylation; 12 h; Inert atmosphere; 2: With methanol in tetrahydrofuran T=0°C; Inert atmosphere; Further stages;
参考文献
Tetrahedron, , vol. 67, # 3 p. 576 - 583
反应条件
benzo[1,3,2]dioxaborole in tetrahydrofuran Heating;
参考文献
Bioorganic and Medicinal Chemistry Letters, , vol. 15, # 11 p. 2803 - 2807
参考文献
Bioorganic and Medicinal Chemistry, , vol. 12, # 15 p. 4285 - 4299
反应条件
water; silica gel T=20°C; 1 h; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 74, # 19 p. 7364 - 7369
反应条件
in not given according to H. C. Brown et al.: J. Am. Chem. Soc. 97 (1975) 5249;
参考文献
Journal of Organometallic Chemistry, , vol. 507, # 1-2 p. 207 - 214
参考文献
Journal of Organometallic Chemistry, , vol. 5, p. 506 - 519
反应条件
(i) MeLi, Et2O, THF, CH2Cl2, (ii) /BRN= 471223/; Multistep reaction;
参考文献
Journal of the American Chemical Society, , vol. 97, # 19 p. 5608 - 5609
反应条件
tetrakis(triphenylphosphine) palladium(0); caesium carbonate in toluene Suzuki coupling; Heating;
参考文献
Eddarir, Said; Cotelle, Nicole; Bakkour, Youssef; Rolando, Christian
Tetrahedron Letters, 2003 , vol. 44, # 28 p. 5359 - 5363
反应条件
tetrakis(triphenylphosphine) palladium(0); copper(I) thiophene-2-carboxylate in tetrahydrofuran T=100°C; Liebeskind-Srogl coupling; 3 h; Inert atmosphereMicrowave irradiation;
参考文献
Arshad, Nuzhat; Hashim, Jamshed; Kappe, C. Oliver
Journal of Organic Chemistry, 2009 , vol. 74, # 14 p. 5118 - 5121
反应条件
tetrabutylammomium bromide; sodium carbonate; palladium diacetate in water T=150°C; Suzuki coupling; 0.0833333 h; microwave irradiation;
参考文献
Arvela, Riina K.; Leadbeater, Nicholas E.; Sangi, Michael S.; Williams, Victoria A.; Granados, Patricia; Singer, Robert D.
Journal of Organic Chemistry, 2005 , vol. 70, # 1 p. 161 - 168