1: PTAS With tetrabutyl ammonium fluoride in tetrahydrofuran; water
T=20°C; 1 h;
2: 2-Chloro-1,3-dimethylbenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water
T=80°C; 12 h;
1: diallyl(diphenyl)silane With tetrabutyl ammonium fluoride in tetrahydrofuran; water
T=20°C; 1 h;
2: 2-Chloro-1,3-dimethylbenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water
T=80°C; 20 h;
trineopentylphosphine; palladium diacetate; sodium carbonate in tetrahydrofuran; water
T=80°C; Suzuki-Miyaura Coupling; 24 h; Inert atmosphereGlovebox;
参考文献
Raders, Steven M.; Moore, Jane N.; Parks, Jacquelynn K.; Miller, Ashley D.; Leissing, Thomas M.; Kelley, Steven P.; Rogers, Robin D.; Shaughnessy, Kevin H.
Journal of Organic Chemistry, 2013 , vol. 78, # 10 p. 4649 - 4664
