1H,1H,2H,2H-全氟-1-癸醇合成路线 （共 46 条）
反应条件
trans-[(2,6-bis(di-tert-butylphosphinomethyl)pyridine)Fe(H)2(CO)]; hydrogen; sodium methylate in 1,4-dioxane T=40°C; P=18751.9 Torr; 16 h; GloveboxInert atmosphere;
参考文献
Zell, Thomas; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4685 - 4689
Angew. Chem., 2014 , vol. 126, # 18 p. 4773 - 4777
反应条件
water; triethylamine in methanol 0.25 h; Ambient temperature;
参考文献
Becker, James Y.; Smart, Bruce E.; Fukunaga, Tadamichi
Journal of Organic Chemistry, 1988 , vol. 53, # 24 p. 5714 - 5720
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
→
反应条件
silver(l) oxide T=100°C; 4 h;
参考文献
US2007/123731 A1, ;
Page/Page column 5 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
silver(l) oxide T=100°C; 4 h;
参考文献
US2007/123731 A1, ;
Page/Page column 5 ;
→
17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 9 ;
反应条件
hydrogenchloride; water T=70°C; pH=0 - 1; 25 h;
参考文献
Paterova, Jana; Skalicky, Martin; Rybackova, Marketa; Kvicalova, Magdalena; Cvacka, Josef; Kvicala, Jaroslav
Journal of Fluorine Chemistry, 2010 , vol. 131, # 12 p. 1338 - 1343
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
→
反应条件
hydrogenchloride; formic acid; oxygen; copper; zinc in water T=80°C; 2 h; various solvents, water concentration; Product distribution;
参考文献
Blancou,H.; Benefice,S.
Journal of Fluorine Chemistry, 1983 , vol. 23, p. 57
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 8-9 ;
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 8-9 ;
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 9-10 ;
