1,3-双(二苯基膦)丙烷合成路线 （共 42 条）
反应条件
in methanol; isopropyl alcohol in hot soln.; drying in vac.;
参考文献
Smeets; Meijer; Meuldijk; Vekemans; Hulshof
Organic Process Research and Development, 2003 , vol. 7, # 1 p. 10 - 16
反应条件
in toluene Product distribution / selectivity;
参考文献
Sumitomo Chemical Company, Limited
Patent: EP1932846 A1, 2008 ;
Location in patent: Page/Page column 8 ;
反应条件
in dichloromethane addn. of 1,3-bis(diphenylphosphino)propane to a stirred soln. of (Ru4Se2(CO)11) in CH2Cl2; stirring for 2 h at room temperature; concn. in vac.;; chromy. (silica-coated plate, CH2Cl2/hexane (2:3)): isolation of an orange band, further isolation of (Ru3(CO)12); elem. anal.;;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 6 p. 973 - 980
反应条件
hydrogenchloride; triethylamine in water; acetonitrile
参考文献
Fotouhi, Nader; Gillespie, Paul; Guthrie, Robert William; Pietranico-Cole, Sherrie Lynn; Yun, Weiya
Patent: US2002/161237 A1, 2002 ;
反应条件
in benzene
40 h; Heating; Yield given;
参考文献
Gurusamy, Narayanasamy; Berlin, K.Darrel; Helm, Dick van der; Hossain, M.Bilayet
Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3107 - 3114
反应条件
1: benzene / 40 h / Heating
2: benzene / 40 h / Heating
View Scheme
参考文献
Gurusamy, Narayanasamy; Berlin, K.Darrel; Helm, Dick van der; Hossain, M.Bilayet
Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3107 - 3114
反应条件
1: benzene / 40 h / Heating
2: 51 percent / 1.) 115percent polyphosphoric acid, 2.) aq. KPF6 / 1.) 180 deg C, 1 h
View Scheme
参考文献
Gurusamy, Narayanasamy; Berlin, K.Darrel; Helm, Dick van der; Hossain, M.Bilayet
Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3107 - 3114
反应条件
1: benzene / 40 h / Heating
2: benzene / 40 h / Heating
3: 45 percent / 1.) 115percent polyphosphoric acid, 2.) aq. KPF6 / 1.) 180 deg C, 1 h
View Scheme
参考文献
Gurusamy, Narayanasamy; Berlin, K.Darrel; Helm, Dick van der; Hossain, M.Bilayet
Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3107 - 3114
反应条件
1: 78 percent / naphthalene, sodium / tetrahydrofuran / 48 h / 0 - 22 °C
2: 92 percent / n-BuLi / tetrahydrofuran / -78 deg C, 40 min, RT, 30 min
View Scheme
参考文献
Chou, Ta-Shue; Tsao, Chung-Huang; Hung, Su Chun
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 53 - 58
反应条件
naphthalene; sodium in tetrahydrofuran
T=0 - 22°C; 48 h;
参考文献
Chou, Ta-Shue; Tsao, Chung-Huang; Hung, Su Chun
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 53 - 58
