2,6-二溴二噻吩[3,2-b:2',3'-d]噻吩合成路线 （共 6 条）
反应条件
N-bromosuccinmide in N,N-dimethyl-formamide T=0 - 20°C; Inert atmosphere;
参考文献
KYUSHU UNIVERSITY NATIONAL UNIVERSITY CORPORATION; ADACHI, Chihaya; Yasuda, Takuma; Yu Seok, Yang; Kakizoe, Hayato; Mieno, Hiroyuki
Patent: US2013/207081 A1, 2013 ;
Location in patent: Paragraph 0081; 0082; 0083 ;
反应条件
1: With lithium hydroxide hydrate in tetrahydrofuran; water 3 h; Reflux; 2: With N-bromosuccinmide in tetrahydrofuran; water T=20°C;
参考文献
Kwon, Tae-Hyuk; Armel, Vanessa; Nattestad, Andrew; MacFarlane, Douglas R.; Bach, Udo; Lind, Samuel J.; Gordon, Keith C.; Tang, Weihua; Jones, David J.; Holmes, Andrew B.
Journal of Organic Chemistry, 2011 , vol. 76, # 10 p. 4088 - 4093
反应条件
1: quinoline; copper / 2 h / 230 °C 2: N-bromosuccinmide; acetic acid View Scheme
参考文献
Journal of Organic Chemistry, , vol. 76, # 10 p. 4088 - 4093
反应条件
tetrakis(triphenylphosphine) palladium(0); caesium carbonate in tetrahydrofuran; water; toluene
Suzuki-Miyaura Coupling; 8 h; Inert atmosphereReflux;
参考文献
Okada, Shinjiro; Yamada, Kenji
Journal of Molecular Structure, 2013 , vol. 1037, p. 256 - 263
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tris-(o-tolyl)phosphine in tetrahydrofuran
T=80°C; Stille Coupling; 24 h; Inert atmosphereSealed tube;
参考文献
OCEAN'S KING LIGHTING SCIENCE and TECHNOLOGY CO., LT D,
Patent: US2012/302763 A1, 2012 ;
Location in patent: Page/Page column 6 ;
反应条件
1.1: LDA / 1 h / -78 °C
1.2: 71 percent / 0.5 h / -78 - 25 °C
2.1: 71 percent / aq. HI / toluene / 25 °C
View Scheme
参考文献
Frey, Joseph; Bond, Andrew D.; Holmes, Andrew B.
Chemical Communications, 2002 , # 20 p. 2424 - 2425
