in water-d2 T=25°C; free energy: -1.06 +/- .16 kcal/mol; determined by 1H NMR (calculation from equilibrium conc.); add. of DMAP as catalyst; Thermodynamic data;
参考文献
Fan, Yun-Hua; Haseltine, John
Tetrahedron Letters, 1996 , vol. 37, # 52 p. 9279 - 9282
1: oct-1-ene With trichlorosilane; dihydrogen hexachloroplatinate in isopropyl alcohol; toluene T=50°C; 2: methanol With urea in isopropyl alcohol; toluene T=50°C;
参考文献
Sakai, Takashi; Hayashi, Kyoko; Yano, Fumika; Takami, Mie; Ino, Megumi; Korenaga, Toshinobu; Ema, Tadashi
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 7 p. 1441 - 1446