1,3-二甲氧基-2-硝基苯合成路线 （共 20 条）
反应条件
potassium carbonate in acetone T=60 - 70°C;
参考文献
US2007/179164 A1, ;
Page/Page column 56 ;
反应条件
oxygen; copper diacetate; silver carbonate in N,N-dimethyl-formamide T=140°C; P=760.051 Torr; 36 h;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 10 p. 2959 - 2962
Angew. Chem., , vol. 125, # 10 p. 3031 - 3035,4
反应条件
potassium carbonate in acetone 1 h; Inert atmosphereReflux;
参考文献
Bioorganic and Medicinal Chemistry, , vol. 19, # 20 p. 6042 - 6054
反应条件
KNO2; copper(II) bis(trifluoromethanesulfonate) in dimethyl sulfoxide T=135°C; 60 h; Inert atmosphereSealed tube; regioselective reaction;
参考文献
Tetrahedron Letters, , vol. 53, # 12 p. 1511 - 1513
反应条件
trifluoromethylsulfonic anhydride; NMe4NO3 in dichloromethane 15 h;
参考文献
Journal of Organic Chemistry, , vol. 68, # 2 p. 267 - 275
反应条件
1: potassium tert-butylate / ethanol / 1 h 2: copper diacetate; silver carbonate; oxygen / N,N-dimethyl-formamide / 36 h / 140 °C / 760.05 Torr View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 10 p. 2959 - 2962
Angew. Chem., , vol. 125, # 10 p. 3031 - 3035,4
反应条件
cerium(IV) ammonium nitrate supported on silica in dichloromethane 0.25 h; Ambient temperature; Yield givenYields of byproduct given;
参考文献
Synthetic Communications, , vol. 29, # 7 p. 1201 - 1208
反应条件
1: concentrated sulfuric acid / 60 - 100 °C / Behandeln mit einem Gemisch von konz. Schwefelsaeure und Salpetersaeure bei 25grad und anschliessendes Einleiten von Wasserdampf 2: aqueous NaOH / <40 View Scheme
反应条件
T=110°C; Diazotieren in alkoholisch-schwefelsaurer Loesung;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 38, p. 108
