1: With KHF2 in methanol; water
T=0 - 20°C; 0.0333333 h; Inert atmosphere;
2: With NOBF4 in acetonitrile
T=20°C; 0.00833333 h; regioselective reaction;
参考文献
Molander, Gary A.; Cavalcanti, Livia N.
Journal of Organic Chemistry, 2012 , vol. 77, # 9 p. 4402 - 4413
1: 1.) 1,2-dibromoethane, magnesium / 1.) benzene, THF, 2.) -45 deg C -> room temperature, 15 min
2: air / chromatography on SiO2
3: 219 mg / CHCl3 / 144 h / Ambient temperature; in the dark
View Scheme
参考文献
Forrester, Alexander R.; Fullerton, Joseph D.; McConnachie, Gordon
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1759 - 1764
