dihydrogen peroxide; acetic acid T=100°C; 2 h;

1: aqueous ethanol 2: H2O2; aqueous acetic acid View Scheme

1: POCl3 2: concentrated aqueous NH3; CuSO4 / 135 °C 3: 225 °C View Scheme

1: 5 percent / POCl3 / 3 h / Heating 2: 1) NaH / 1a) DMSO, RT, 1b) 70 deg C, 2) RT View Scheme

trichlorophosphate

trichlorophosphate T=80°C;

trichlorophosphate 3 h; Heating;

暂无反应条件数据

1: POCl3 2: concentrated aqueous HCl 3: 230 °C View Scheme

1: 67 percent / dimethylcarbamyl chloride / toluene / 20 h / 60 °C 2: 74 percent / HBr / acetic acid / 1 h / 25 °C 3: 90 percent / bis(dibenzylideneacetone)palladium; triphenylphosphine; aq. K2CO3 / toluene; dimethylformamide / 4 h / Heating 4: 60 percent / sodium nitrite / dimethylformamide / 3 h / 25 °C 5: 94 percent / bis(dibenzylideneacetone)palladium; triphenylphosphine; 2 N aq. Na2CO3 / tetrahydrofuran / 2 h / 80 °C View Scheme