3,3,3-三氟-1-丙炔合成路线 (共 80 条)
反应条件
hydrogen fluoride; fluorinated Cr2O3 T=275 - 335°C; P=863.483 Torr; Inert atmosphereGas phase; Product distribution / selectivity;
参考文献
US2012/172636 A1, ;
Page/Page column 4-5 ;
参考文献
Journal of the American Chemical Society, , vol. 73, p. 1042
Journal of the Chemical Society, , p. 2495,2503
反应条件
zinc(II) chloride; lithium diisopropyl amide in tetrahydrofuran T=-78°C; Inert atmosphere;
参考文献
Journal of Medicinal Chemistry, , vol. 54, # 9 p. 3393 - 3417
反应条件
triethylamine in acetone T=27°C; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 18 p. 7359 - 7369
反应条件
fluorinating chromium oxide (~12.2 wt.percent F) T=380°C; Product distribution / selectivity;
参考文献
WO2010/50373 A2, ;
Page/Page column 20; 22 ;
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 1,) 0 deg C, 2.) 0.5 h, room temp.;
参考文献
Tetrahedron Letters, , vol. 26, # 1 p. 79 - 82
反应条件
KF on alumina T=400 - 500°C; Inert atmosphere; Product distribution / selectivity;
参考文献
WO2010/95764 A1, ;
Page/Page column 9-10 ;
反应条件
CsF/C T=350 - 500°C; Inert atmosphere; Product distribution / selectivity;
参考文献
WO2010/95764 A1, ;
Page/Page column 7-9 ;
反应条件
potassium hydroxide T=120 - 150°C;
参考文献
Journal of the Chemical Society, , p. 584,587
反应条件
hydrogen fluoride; titanium tetrachloride Product distribution / selectivity;
参考文献
US2012/172636 A1, ;
Page/Page column 5 ;