tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide 2 h; Ambient temperature;

palladium; triethyl phosphite in tetrahydrofuran 0.5 h; Ambient temperature;

tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenylphosphine in tetrahydrofuran 0.333333 h; Ambient temperaturealso cat. Pd(O)-P(OEt)3; reaction time and temperature; allyl β-keto-carboxylates with allylic carbonates; new method for the diallylation of ketones; Product distributionMechanism;

1.) DMF, 50 deg C; Yield given. Multistep reaction;

Cu(I)-tert-butoxide 1.) THF, -10 deg C, 7h, 2.) DMF, 0 deg C to r.t.; Yield given. Multistep reaction;

multistep reaction; reaction with HOCO2Cu-(PEt3)3; Product distribution;

tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide 2 h; Ambient temperature;