tert.-butylhydroperoxide; 5,10,15,20-tetrakisphenylporphyrinatoiron(III) chloride in dichloromethane T=30°C; Title compound not separated from byproducts;

1: t-BuOOH; 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride / CH2Cl2 / 30 °C 2: chlorotrimethylsilane / 18 h / Heating 3: tetrahydrofuran / 12 h 4: t-BuOOH; 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride / CH2Cl2 / 30 °C View Scheme

tert.-butylhydroperoxide; 5,10,15,20-tetrakisphenylporphyrinatoiron(III) chloride in dichloromethane T=30°C; Title compound not separated from byproducts;

tert.-butylhydroperoxide; silver hexafluoroantimonate; [Pd(Quinox)Cl2] in dichloromethane; water T=20°C; 16 h; Darkness;

Rhodium trichloride in ethanol T=95°C; 36 h; Yield given. Yields of byproduct given;

palladium (II) trifluoroacetate; 1,3-bis-(diphenylphosphino)propane in acetonitrile T=80°C; Reactivity; Reagent/catalystSolvent;