[[O-(烯丙氧基)苯氧基]甲基]环氧乙烷合成路线 （共 5 条）
反应条件
1: O-allyl-catechol With sodium hydride in N,N-dimethyl-formamide
T=0°C; Metallation;
2: oxiran-2-ylmethyl 4-methyl-1-benzenesulfonate in N,N-dimethyl-formamide
Alkylation;
参考文献
Apparu, Marcel; Ben Tiba, Younes; Leo, Pierre-Marc; Hamman, Sylvain; Coulombeau, Christian
Tetrahedron Asymmetry, 2000 , vol. 11, # 14 p. 2885 - 2898
反应条件
sodium hydride in N,N-dimethyl-formamide; mineral oil
T=0 - 20°C;
参考文献
Kong, Xu-Dong; Ma, Qian; Zhou, Jiahai; Zeng, Bu-Bing; Xu, Jian-He
Angewandte Chemie - International Edition, 2014 , vol. 53, # 26 p. 6641 - 6644
Angew. Chem., 2014 , p. 6759 - 6762,4
反应条件
1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 - 20 °C
2: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 - 20 °C
View Scheme
参考文献
Kong, Xu-Dong; Ma, Qian; Zhou, Jiahai; Zeng, Bu-Bing; Xu, Jian-He
Angewandte Chemie - International Edition, 2014 , vol. 53, # 26 p. 6641 - 6644
Angew. Chem., 2014 , p. 6759 - 6762,4
反应条件
ammonia; potassium carbonate in methanol; acetone; benzene
参考文献
Cassella Farbwerke Mainkur Aktiengesellschaft
Patent: US3969363 A1, 1976 ;
反应条件
ammonia; sodium ethanolate; potassium carbonate in methanol; acetone; benzene
参考文献
Cassella Farbwerke Mainkur Aktiengesellschaft
Patent: US4018778 A1, 1977 ;
